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AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: <strong>7783</strong>-<strong>20</strong>-2<br />

DATE: 18.04.<strong>20</strong>06<br />

3.1.1 Photodegradation<br />

Remark:<br />

Ammonium sulfate is not photodegraded. It can be formed in<br />

atmospheric aerosols from the interaction of atmospheric<br />

ammonia with atmospheric SO2.<br />

22-MAY-<strong>20</strong>03 (26) (17)<br />

3.1.2 Stability in Water<br />

Type:<br />

abiotic<br />

Remark:<br />

In aqueous solution, ammonium sulfate is completely<br />

dissociated into the ammonium ion (NH4+) and the sulfate anion<br />

(SO42-). Depending on pH, ammonia (NH3) exists in equilibrium<br />

with the ammonium ion (NH4+), according to the following<br />

relationship:<br />

NH4+ + H2O NH3 + H3O+<br />

In general, as pH increases, the fraction of the total ammonia<br />

which is un-ionized increases. For example, at 5 °C and pH<br />

6.5, 0.0395% of the total ammonia is present as NH3.<br />

Increasing the pH from 6.5 to 8.5 will increase the un-ionized<br />

ammonium by a factor of approximately 100 (Rice and Bailey<br />

1980). Increasing the temperature will also increase the<br />

percentage of unionized ammonium. For example, in seawater at<br />

25 °C and pH of approximately 8.1, approximately 7% of the<br />

total ammonia is present as NH3.<br />

Reliability: (2) valid with restrictions<br />

Flag:<br />

Critical study for SIDS endpoint<br />

12-JUL-<strong>20</strong>04 (27) (28)<br />

3.1.3 Stability in Soil<br />

3.2.1 Monitoring Data (Environment)<br />

Type of measurement: background concentration<br />

Medium:<br />

air<br />

Method:<br />

Result:<br />

Fine (

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