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AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: <strong>7783</strong>-<strong>20</strong>-2<br />

DATE: 18.04.<strong>20</strong>06<br />

treated catchment showed that soils were the dominant sink<br />

for the labeled ammoniun. Surface soils (Oea horizon plus<br />

any underlying mineral soil to 5 cm depth) assimilated 19 to<br />

31 percent of the 42 kg/ha of labeled ammonium-N additions.<br />

Of the three forest types on the catchment, the soil:<br />

biomass assimilation ratio of labeled-N was highest in the<br />

spruce forest, intermediate in the beech-dominated hardwood<br />

forest and lowest in the mixed hardwood-spruce forest.<br />

Although ammonium sulfate additions led to increases in<br />

streamwater nitrate, only 2 of the 13 kg/ha of nitrate-N<br />

exported from the catchment during the 2 years of tracer<br />

additions was derived from the 42 kg/ha of labeled<br />

ammonium-N addition.<br />

Reliability: (1) valid without restriction<br />

study well documented and assignable<br />

28-MAY-<strong>20</strong>04 (41)<br />

Media:<br />

soil-biota-air<br />

Method:<br />

Various N fertilizers were applied to winter wheat under<br />

field conditions. Ammonium sulfate was distributed at the<br />

beginning of tillering, and was tested at 16 g N/m2 in a<br />

microplot experiment. Gas traps of 4.4 dm3 were laid between<br />

the rows of the microplots and ammonia, nitric oxide, nitrous<br />

oxide, dinitrogen oxide and nitrogen contents of trapped soil<br />

air were analyzed by gas chromatography duringn vegetation.<br />

Result:<br />

The N losses measured at the different samplings were not<br />

higher than 1.2% of the N doses applied in the field. The<br />

complete transformation of the fertilizers took place<br />

practically within 11 weeks after their distribution to<br />

wheat grown in the field. The composition of the nitrogenous<br />

gases changed during vegetation depending on the applied<br />

fertilizer. The proportion of N2O increased within the total<br />

amount of nitrogenous gases in the field traps. Among the<br />

nitrogenous gases tested, N2 showed by far the highest and NO<br />

the lowest concentration.<br />

Test condition: slightly acidic brown forest soil<br />

measurement period: 13, 41, 62, 76 and 108 d<br />

Reliability: (1) valid without restriction<br />

study well documented and assignable<br />

28-MAY-<strong>20</strong>04 (45)<br />

Type of measurement: other: leaching from soil<br />

Media:<br />

leachate from lysimeter<br />

Method:<br />

An identical experimental protocol was followed in six<br />

European coniferous forest soils, with different soil<br />

characteristics, pollution histories and climate, to measure<br />

the effects of enhanced (NH4)2SO4 deposition on lysimeter<br />

throughfall. The sites are located in: Clonegal (IRL) - brown<br />

soil, clay/silty clay, stand = Picea abies, cation exchange<br />

buffer range, C/N 14.5, past N input 9.6 kg/ha/a, pHH2O<br />

4.2.Fontainebleau (FR), - Podsol soil, loamy sand, stand =<br />

Pinus sylvestris, aluminium buffer range, C/N 27.0, past N<br />

input 10.5 kg/ha/a, pHH2O 3.9.Grizedale (UK) - brown soil,<br />

clay, stand = Picea abies, aluminium buffer range, C/N 15.8,<br />

past N input 13.3 kg/ha/a, pHH2O 3.7.Haldon (UK) -brown soil,<br />

clay loam, stand = Picea abies, cation exchange buffer range,<br />

C/N 13.8, past N input 17.3 kg/ha/a, pHH2 4.3.Solling (DE) -<br />

UNEP PUBLICATIONS 73

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