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AMMONIUM SULFATE CAS N°: 7783-20-2

AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: <strong>7783</strong>-<strong>20</strong>-2<br />

DATE: 18.04.<strong>20</strong>06<br />

Type of measurement: background concentration<br />

Medium:<br />

sediment<br />

Remark:<br />

Ammonium sulfate is found naturally in volcanic craters.<br />

Flag:<br />

Critical study for SIDS endpoint<br />

26-JAN-<strong>20</strong>04 (10)<br />

Type of measurement: background concentration<br />

Remark:<br />

In the frame of the German water quality monitoring program<br />

ammonium nitrogen concentrations were measured. In <strong>20</strong>00, the<br />

rivers Danube, Oder, Weser, Rhine, and Elbe showed<br />

concentrations (50th percentile) ranging from 0.04 to 0.07<br />

mg/l.<br />

UBA states that in Germany 624 000 t ammonia were emitted to<br />

air in 1999<br />

23-AUG-<strong>20</strong>05 (31)<br />

Type of measurement: concentration at contaminated site<br />

Medium:<br />

other: rainwater<br />

Method:<br />

Remark:<br />

Result:<br />

Test substance:<br />

Reliability:<br />

Monthly bulk precipitation samples were collected on a rural<br />

coastal island located 8-10 km from the NL mainland, for<br />

more than 15 years (May 1972 - December 1987). Comparative<br />

samples for an urban environment were obtained from a region<br />

southeast of Amsterdam, for the years 1973-1982 inclusive.<br />

Monthly bulk precipitation<br />

Higher levels of ammonium and sulfate in bulked rainwater<br />

were found in the coastal island rural environment than at<br />

Ouderkerk. The higher rural concentration of ammonium at<br />

Schiermonnikoog is ascribed to dry deposited NH3 in the<br />

collectors, due to substantial cattle breeding.<br />

The precipitation weighted averages of monthly concentreations<br />

of the dissolved substances in bulk precipitation for<br />

Schiermonnkoog during May 1972 - 1987 were 2.684 mg/l (<br />

converted from 149.1 µmol/l) and 6.65 mg/l (converted from<br />

69.3 µmol/l) respectively, with seasonal variations showing<br />

higher values in late winter/early spring, and lower values in<br />

autumn. For Ouderkerk no concentrations were reported.<br />

ammonium and sulfate, obtained from rainwater.<br />

(1) valid without restriction<br />

study well documented and assignable<br />

Critical study for SIDS endpoint<br />

Flag:<br />

28-MAY-<strong>20</strong>04 (32)<br />

Type of measurement: other: calculation of consumer exposure<br />

Remark:<br />

Sulfates are natural components of food; ammonium sulfate is<br />

"generally recognized as safe (GRAS)" and approved as a food<br />

additive in the U.S. (FDA <strong>20</strong>03) and in Europe (E 517; EU,<br />

1995). From this data it can be seen that consumer exposure to<br />

sulfate is low: 453 mg per day via food, 48 mg per day via<br />

drinking water assuming 2 l drinking water per day and 0.63 ug<br />

per day via air assuming <strong>20</strong> m3 respiratory volume. Ammonia<br />

intake via food is 18 mg/day. Endogenous production of ammonia<br />

(4000 mg/day) is about 2 orders of magnitude higher than<br />

exogenous intake (ammonia and ammonium) via food (<strong>20</strong> mg/day),<br />

air (< 1 mg/day) and water (< 1mg/day) (WHO, 1986, 1996,<br />

UNEP PUBLICATIONS 67

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