AMMONIUM SULFATE CAS N°: 7783-20-2
AMMONIUM SULFATE CAS N°: 7783-20-2
AMMONIUM SULFATE CAS N°: 7783-20-2
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OECD SIDS<br />
<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />
3. ENVIRONMENTAL FATE AND PATHWAYS ID: <strong>7783</strong>-<strong>20</strong>-2<br />
DATE: 18.04.<strong>20</strong>06<br />
Type of measurement: background concentration<br />
Medium:<br />
sediment<br />
Remark:<br />
Ammonium sulfate is found naturally in volcanic craters.<br />
Flag:<br />
Critical study for SIDS endpoint<br />
26-JAN-<strong>20</strong>04 (10)<br />
Type of measurement: background concentration<br />
Remark:<br />
In the frame of the German water quality monitoring program<br />
ammonium nitrogen concentrations were measured. In <strong>20</strong>00, the<br />
rivers Danube, Oder, Weser, Rhine, and Elbe showed<br />
concentrations (50th percentile) ranging from 0.04 to 0.07<br />
mg/l.<br />
UBA states that in Germany 624 000 t ammonia were emitted to<br />
air in 1999<br />
23-AUG-<strong>20</strong>05 (31)<br />
Type of measurement: concentration at contaminated site<br />
Medium:<br />
other: rainwater<br />
Method:<br />
Remark:<br />
Result:<br />
Test substance:<br />
Reliability:<br />
Monthly bulk precipitation samples were collected on a rural<br />
coastal island located 8-10 km from the NL mainland, for<br />
more than 15 years (May 1972 - December 1987). Comparative<br />
samples for an urban environment were obtained from a region<br />
southeast of Amsterdam, for the years 1973-1982 inclusive.<br />
Monthly bulk precipitation<br />
Higher levels of ammonium and sulfate in bulked rainwater<br />
were found in the coastal island rural environment than at<br />
Ouderkerk. The higher rural concentration of ammonium at<br />
Schiermonnikoog is ascribed to dry deposited NH3 in the<br />
collectors, due to substantial cattle breeding.<br />
The precipitation weighted averages of monthly concentreations<br />
of the dissolved substances in bulk precipitation for<br />
Schiermonnkoog during May 1972 - 1987 were 2.684 mg/l (<br />
converted from 149.1 µmol/l) and 6.65 mg/l (converted from<br />
69.3 µmol/l) respectively, with seasonal variations showing<br />
higher values in late winter/early spring, and lower values in<br />
autumn. For Ouderkerk no concentrations were reported.<br />
ammonium and sulfate, obtained from rainwater.<br />
(1) valid without restriction<br />
study well documented and assignable<br />
Critical study for SIDS endpoint<br />
Flag:<br />
28-MAY-<strong>20</strong>04 (32)<br />
Type of measurement: other: calculation of consumer exposure<br />
Remark:<br />
Sulfates are natural components of food; ammonium sulfate is<br />
"generally recognized as safe (GRAS)" and approved as a food<br />
additive in the U.S. (FDA <strong>20</strong>03) and in Europe (E 517; EU,<br />
1995). From this data it can be seen that consumer exposure to<br />
sulfate is low: 453 mg per day via food, 48 mg per day via<br />
drinking water assuming 2 l drinking water per day and 0.63 ug<br />
per day via air assuming <strong>20</strong> m3 respiratory volume. Ammonia<br />
intake via food is 18 mg/day. Endogenous production of ammonia<br />
(4000 mg/day) is about 2 orders of magnitude higher than<br />
exogenous intake (ammonia and ammonium) via food (<strong>20</strong> mg/day),<br />
air (< 1 mg/day) and water (< 1mg/day) (WHO, 1986, 1996,<br />
UNEP PUBLICATIONS 67