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AMMONIUM SULFATE CAS N°: 7783-20-2

AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

4. ECOTOXICITY ID: <strong>7783</strong>-<strong>20</strong>-2<br />

DATE: 18.04.<strong>20</strong>06<br />

Five eggs in each container and 40 spawn per concentration<br />

were used. Same methods were employed for spawn and fry of<br />

fish. Tests were repeated six times accompanied with<br />

ocntrols. No death of eggs, spwan and fry were observed in<br />

controls.<br />

Reliability: (2) valid with restrictions<br />

limited documentation, concentration range not reported<br />

02-FEB-<strong>20</strong>04 (65)<br />

Type:<br />

static<br />

Species:<br />

Ictalurus punctatus (Fish, fresh water)<br />

Exposure period: 24 hour(s)<br />

Unit: mg/l Analytical monitoring: yes<br />

Limit Test: no<br />

Method: other: similar to those suggested by the USEPA (1975)<br />

GLP:<br />

no data<br />

Test substance: other TS: ammonium sulfate, not further specified<br />

Result:<br />

When compared on the basis of un-ionized ammonia nitrogen<br />

(NH3-N), ammonium chloride solutions were more toxic than<br />

ammonium sulfate solutions. Median lethal concentrations<br />

(24h- LC50s) at pH 8.8, 8.0, 7.2 and 6.0 were, respecitvely,<br />

1.91, 1.45, 1.04, and 0.74 mg NH3-N/L for ammonium chloride,<br />

and 2.24, 1.75, 1.16, and 0.81 mg NH3-N/L for ammonium<br />

sulfate. Ionized ammonia (NH4) was not lethal at<br />

concentrations up to 1787 mg NH4-N/L.<br />

The author conclude that based on acute toxicity tests that<br />

account for osmotic effects, NH4+ must be considered an<br />

essentially nontoxic substance. The apparent increase in<br />

toxicity of NH3 to channel catfish at lower pH is due to<br />

osmotic effects of toxicant formulations, rather than<br />

specifically to NH4.<br />

Test condition: 8 static 24-h median lethal tests were conducted with 16-g<br />

channel catfish. Fish were acclimated for at least 2 weeks<br />

prior to testing. Feeding was stopped one week before use in<br />

tests (minimize ammonia excretion by the fishes).<br />

The 110-Liter aquaria held 80 liters of 21 °C water at various<br />

pHs (6.0, 7.2, 8.0, 8.8). Each exposure group consisted of 10<br />

fish. Buffers were added and fish acclimated for 24 hours<br />

before ammonia (as ammonium sulfate or ammonium chloride) was<br />

added.<br />

Reliability: (2) valid with restrictions<br />

limited documentation; 24-hour LC50 tests used.<br />

23-JAN-<strong>20</strong>04 (66)<br />

Type:<br />

static<br />

Species:<br />

Oncorhynchus gorbuscha (Fish, fresh water)<br />

Exposure period: 96 hour(s)<br />

Unit: mg/l Analytical monitoring:<br />

LC50: ca. 770<br />

GLP:<br />

Result:<br />

no data<br />

Late alevins (completion of yolk absorption) were the most<br />

sensitive and had the lowest 96-hour LC50 values.<br />

Concentrations as low as 1.2 ppb reduced fry weight in the<br />

61 day exposures. Only levels > 10 ppb stimulated early<br />

UNEP PUBLICATIONS 91

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