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AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

Conclusion<br />

Nitrification during sewage treatment plant operation involves both sensitive (no growth at 4700 but<br />

growth at 94 mg/l ammonium sulfate) and insensitive (growth at 4700 mg/l ammonium sulfate)<br />

strains of Nitrobacter spp (Suwa et al., 1994). This indicates that a NOEC for specific nitrifying<br />

bacteria will be greater than 94 mg/l.<br />

Nitrogen fixation and total soil biomass (but not soil base respiration rate) can be affected by<br />

ammonium sulfate applied at 82.5 kg/ha or more.<br />

4.2 Terrestrial Effects<br />

Toxicity to terrestrial plants<br />

Valid test results are available for four plant species exposed to excessive amounts of ammonium<br />

sulfate. In two examples ammonium sulfate is applied in solid form, while in the others the<br />

application is from aqueous solution and as an atmospheric aerosol.<br />

The effect of ammonium sulfate solution on seed germination was studied for Avena sterilis spp<br />

macrocarpa Mo, in a 21 day test (Gonzalez Ponce and Salas, 1989). Seeds were wrapped with filter<br />

paper which was wetted with ammonium sulfate-solutions of 100 to 5000 mg/l. No significant<br />

increase in germination was found up to 2500 mg/l, compared with the control. An inhibitory effect<br />

was found at 5000 mg/l ammonium sulfate probably caused by a salt effect.<br />

The effect of ammonium sulfate addition on the growth of the onion Allium cepa L. has been<br />

studied under laboratory conditions in 4 Canadian soils, in the presence of lime to raise the soil pH<br />

to approximately 6.5 (Abbés et al., 1995). After 84 days in a growth chamber, immature plants were<br />

harvested and fresh and dry weight of all plant parts were determined. Yield was greatest for<br />

626 mg ammonium sulfate / kg soil (calculated from 133 mg N / kg soil). An inhibitory effect was<br />

found at 1880 and 2506 mg ammonium sulfate / kg soil (calculated from 399 and 532 mg N / kg<br />

soil), except for the sandy soil where only 2506 mg ammonium sulfate / kg soil was inhibitory. In<br />

general such observations could be explained by salt effects.<br />

14 day old pinto bean plants (Phaseolus vulgaris L.) exposed to 26 mg/m 3 ammonium sulfate<br />

aerosol for up to 3<strong>20</strong> hours (ca. 13 days) in an environmental growth chamber showed no changes<br />

in plant biomass or leaf area. However, visible foliar injury occurred, and both abaxial and adaxial<br />

leaf resistances were decreased from control values (Gmur, Evans and Cunningham, 1983). The<br />

ammonium sulfate application rate is stated to be about 2 orders of magnitude above ambient<br />

episode concentration.<br />

The 6 year effect of ammonium sulfate spread as a solid fertilizer was investigated in a stand of<br />

trees (Picea abies, 12 years old at the beginning of the test) in southern Sweden (Rosengren-Brinck<br />

and Nihlgard, 1995). Spreading at 471 kg ammonium sulfate (calculated from 100 kg N) per ha per<br />

year affected resistance to drought, which was evident in a reduction in the flushing of new shoots.<br />

34<br />

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