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AMMONIUM SULFATE CAS N°: 7783-20-2

AMMONIUM SULFATE CAS N°: 7783-20-2

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OECD SIDS<br />

<strong>AMMONIUM</strong> <strong>SULFATE</strong><br />

1. GENERAL INFORMATION ID: <strong>7783</strong>-<strong>20</strong>-2<br />

DATE: 18.04.<strong>20</strong>06<br />

Type:<br />

use<br />

Remark:<br />

Ammonium sulfate is used predominantly as a fertilizer. As a<br />

fertilizer, (NH4)2SO4 has the advantage of adding sulfur to<br />

the soil as well as nitrogen, as it contains 21 % by weight<br />

nitrogen and 24 % by weight sulfur.<br />

Ammonium sulfate is also used in electric dry cell batteries,<br />

as a soldering liquid, as a fire retardant for fabrics and<br />

other products and as a source of certain ammonium chemicals.<br />

Other uses include water treatment, fermentation processes,<br />

fireproofing agents and leather tanning.<br />

Flag:<br />

non confidential, Critical study for SIDS endpoint<br />

26-MAY-<strong>20</strong>03 (5)<br />

Type:<br />

use<br />

Remark:<br />

batteries-, photo- and glass-industry<br />

Flag:<br />

non confidential, Critical study for SIDS endpoint<br />

11-MAY-<strong>20</strong>04 (6)<br />

1.7.1 Detailed Use Pattern<br />

1.7.2 Methods of Manufacture<br />

Orig. of Subst.: Synthesis<br />

Type:<br />

Production<br />

Remark:<br />

Flag:<br />

Large-scale industrial processes (of caprolactam) are,<br />

without exception, multistage processes in which ammonium<br />

sulfate and sometimes organic compounds are formed as<br />

byproducts.<br />

non confidential, Critical study for SIDS endpoint<br />

04-APR-<strong>20</strong>02 (6)<br />

Orig. of Subst.: Synthesis<br />

Type:<br />

Production<br />

Remark:<br />

Ammonium sulfate was originally manufactured by using<br />

sulphuric acid to scrub by-product ammonia from coke-oven gas,<br />

and much is still produced in this manner.<br />

Most of the ammonium sulfate produced is now made by reaction<br />

between synthetic ammonia and sulfuric acid.<br />

2NH3 + H2SO4 -> (NH4)2SO4<br />

Where sulfur for sulfuric acid is at a premium, a process<br />

based on gypsum and carbon dioxide from combustion can be<br />

used:<br />

(NH4)2CO3 + CaSO4*2H2O -> CaCO3 + 2H2O + (NH4)2SO4<br />

Water is removed by evaporation, and the product is<br />

crystallized to large, white uniform crystals.<br />

Anhydride (CaSO4) can also be used in this process.<br />

UNEP PUBLICATIONS 53

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