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Series editors' preface - Wood Tools

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may cause irreparable damage. Applications<br />

which result in a deposit on the surface of an<br />

object will kill adults as they emerge, whilst<br />

insecticide in solution may be injected into<br />

wormholes to kill larvae and act as a residual<br />

treatment. It has been suggested that such<br />

contact or ingestion poisons provide protection<br />

for an extended time and therefore are<br />

more desirable than curative methods. This<br />

may not be true and it may not be desirable.<br />

The effectiveness of these liquid toxic materials<br />

largely depends upon the penetration rate<br />

of the liquid and on whether the entire piece<br />

is being treated or just a part of it.<br />

When using insecticides it is the responsibility<br />

of the conservator to be fully aware of the<br />

hazard presented and to take adequate<br />

precautionary measures. These may include<br />

the use of suitable gloves, mask and coat and<br />

maintaining a high standard of personal and<br />

workshop hygiene. It is essential when using<br />

insecticides to follow the guidelines for safe<br />

use set out by the manufacturer. Ware (1988)<br />

and CCI Technical Bulletin 15 (1992) list<br />

numerous insecticides and pesticides which<br />

have been used to treat organic materials.<br />

Insecticidal treatments have been used since<br />

the nineteenth century to control insect infestation.<br />

An overview of historical materials and<br />

methods is given by Unger et al. (2001) and<br />

Schiessl (1984). As side effects which are<br />

harmful to humans become known, insecticides<br />

are taken off the domestic market. An<br />

example of this was the insecticide lindane<br />

(hexachlorocyclohexane), which was widely<br />

used from the 1950s through to the early<br />

1980s. Although an effective insecticide, its<br />

high vapour pressure resulted in it subliming<br />

off treated material over time. Concerns over<br />

long-term toxic and carcinogenic effects<br />

resulted in its withdrawal. Synthetic<br />

pyrethroids have been widely used to treat<br />

anobium infestations since the mid 1980s<br />

because they combine low mammalian toxicity,<br />

highly insecticidal properties which allow<br />

low dosage treatments, are odourless and do<br />

not stain (Pinniger and Child, 1996). However<br />

some research has connected their use with<br />

increased incidence of cancer (Nicholson,<br />

1997). It may be necessary to label objects<br />

which have been treated with a residual pesticide<br />

to avoid any potential health and safety<br />

hazards for future handlers or conservators.<br />

General review of environment and deterioration 271<br />

Dichlorvos vapour (2,2, dimethyl dichlorovinyl<br />

phosphate) from insecticidal strips has<br />

proven to be effective against emerging adults.<br />

Such strips are particularly suitable for storage<br />

or display areas which are comparatively<br />

undisturbed and allow the slow and sustained<br />

release necessary for pesticidal effectiveness.<br />

Strips should not be placed in contact with<br />

objects. In the presence of moisture dichlorvos<br />

hydrolyses readily to form acidic<br />

compounds. At high RH (>70%) it is potentially<br />

damaging to metals and may cause<br />

natural resins, glues and plastics to become<br />

tacky and acid and disperse red dyes are also<br />

vulnerable to damage. Dichlorvos has a short<br />

term exposure limit (STEL).<br />

Rentokil plc have developed a method<br />

which deposits a very low concentration of<br />

boric acid on exposed timber. This treatment<br />

is usually effective over a period of several<br />

years but will not prevent damage by larvae<br />

which will remain active until they emerge as<br />

adults and are killed.<br />

Fumigants Toxic gases that have most<br />

commonly been used as fumigants for insect<br />

infestations in furniture include methyl bromide,<br />

ethylene oxide and phosphine, although<br />

sulphuryl fluoride, hydrogen cyanide, carbon<br />

disulphide and ethylene chloride have also<br />

been used. These materials have good<br />

penetration and are effective in treating complex<br />

furniture constructions and upholstery.<br />

They are not persistent, that is they do not<br />

prevent reinfestation, but they act quickly and<br />

have a high kill rate on all stages of the insect<br />

life cycle. The risk of staining is low compared<br />

to the use of solvent-based insecticidal formulations<br />

and the use of adhesives and coatings<br />

can proceed immediately after use. They have<br />

provided good results as a first line attack.<br />

However, they are highly toxic to other organisms,<br />

including people, and require special<br />

apparatus and fully trained and qualified<br />

personnel to be used safely.<br />

There is a growing body of evidence that<br />

such materials are damaging to the environment<br />

and in some case to the objects being<br />

fumigated (Burgess and Binnie, 1991; Dow,<br />

undated; Florian, 1987; Koestler 1993). Methyl<br />

bromide for example has contributed to the<br />

destruction of the ozone layer and may damage<br />

some materials as it weakens chemical bonds

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