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Series editors' preface - Wood Tools

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e used cautiously and with suitable health<br />

and safety precautions. A wide range of colour<br />

effects may be achieved, from yellow to a dark<br />

reddish brown depending on the species of<br />

timber, so some experimentation may be<br />

needed to achieve the desired result.<br />

Ammonia (NH 3) is a gas at room temperature<br />

and is soluble in both water and alcohol.<br />

When dissolved in water it forms ammonium<br />

hydroxide (NH 4OH) and it is in this form that<br />

it is usually used. Ammonium hydroxide was<br />

traditionally used to darken woods that<br />

contain tannic acid. Tannic acid may be used<br />

in conjunction with ammonium hydroxide or<br />

with iron salts to form a brown stain that can<br />

be applied to wood. Tannic acid can be<br />

painted onto a surface as a pre-treatment,<br />

although if this step is necessary the stain may<br />

prove to be fugitive. Ammonia is extremely<br />

unpleasant to use, so although brushing a<br />

large surface is possible, it was generally more<br />

practicable to enclose an object and expose it<br />

to ammonia fumes. Fuming had the additional<br />

advantage that it did not raise the grain of the<br />

wood. A test piece may be used to check the<br />

progress of colour change. Exposure to<br />

ammonia fumes will corrode or discolour<br />

many metals and other susceptible materials.<br />

Sodium carbonate (household washing<br />

soda, Na 2CO 3) may be used to produce an<br />

aged effect on some woods. It is one of the<br />

few materials that will effectively colour the<br />

rays of oak.<br />

Solvent borne stains Water stains used in the<br />

past by furniture restorers, such as Vandyke or<br />

walnut crystals, were derived from natural<br />

materials. Most exhibited poor lightfastness<br />

and poor resistance to acids and alkalis. In<br />

addition they are not compatible with many<br />

modern lacquers and these properties lead<br />

most traditional materials to be defined as<br />

‘poor quality’ stains. The term Vandyke brown<br />

may refer to a pigment that is a bituminous<br />

ferruginous earth, Cassel brown treated with<br />

aqueous sodium carbonate or ground and<br />

fermented walnut shells. Modern water stains<br />

may be based on organo-metallic dyes,<br />

complexes of chromium, cobalt or copper<br />

with organic molecules, which vary considerably<br />

in their lightfastness. Some manufacturer’s<br />

water stains are not dyes but are based on<br />

microfine pigments. Other chemical types are<br />

Conserving transparent coatings on wood 619<br />

also used and it may be necessary to contact<br />

the manufacturer or supplier for technical<br />

specifications and information about chemical<br />

stability, lightfastness and compatibility with<br />

coating materials.<br />

Water stains may bead slightly on application<br />

to bare wood. Some manufacturers<br />

recommend the addition of a small amount of<br />

ammonia to reduce surface tension and<br />

increase penetration (20 ml ammonia to a litre<br />

of water stain). The addition of a surfactant<br />

such as Photo-Flo may be useful in promoting<br />

even wetting of the surface. Water stains are<br />

easy to apply and accept all types of traditional<br />

coatings. They may be applied to bare<br />

wood but can also be applied between sealing<br />

coats during retouching using the method<br />

outlined below.<br />

Traditional water stains are prepared by<br />

mixing about 30 g of powder in a litre of<br />

water. Modern water stains should be mixed<br />

according to the manufacturer’s instructions.<br />

Brush, rag or spray application may be used,<br />

and any excess wiped away along the grain<br />

with a rag. A surface coating may be applied<br />

after about 12 hours if the atmosphere in the<br />

workshop is warm and dry. The application of<br />

a water stain to bare wood swells the wood<br />

fibres and raises the grain. This effect can be<br />

minimized by pre-wetting the area to be<br />

stained, allowing it to dry, and then abrading<br />

the uneven surface with 180 grit paper along<br />

the grain. Once the stain has dried, a sealing<br />

coat can be applied and allowed to dry. The<br />

surface can then be lightly abraded to remove<br />

any further raised grain caused by the application<br />

of the water stain. Subsequent coats of<br />

surface coating will need only the usual denibbing<br />

with 240 or 400 grit paper between coats.<br />

As their name implies, spirit stains are<br />

soluble in alcohol and as a result are very<br />

quick-drying. They can be sprayed onto a<br />

large surface but are not generally brushed<br />

onto bare wood because overlapping strokes<br />

produce a streaky effect. They were generally<br />

used for tinting alcohol-soluble varnishes or<br />

for adjusting colour during French polishing.<br />

Spirit stains described in twentieth century<br />

finishing manuals usually consisted of an<br />

aniline dye dissolved in ethyl alcohol or a<br />

similar solvent. They were notorious for their<br />

tendency to fade, particularly the reds, and<br />

were considered ‘fugitive’. Modern stains that

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