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Series editors' preface - Wood Tools

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Cleaning tests may embrace a wide range of<br />

techniques such as mechanical cleaning, dry<br />

cleaning, solvent and aqueous cleaning<br />

(including the manipulation of pH, conductivity,<br />

and/or the addition of chelating agents,<br />

enzymes, detergents or surfactants). A cotton<br />

swab or the corner of a lint-free cotton cloth<br />

may be a convenient way to apply test material.<br />

If cleaning solutions are used, the test<br />

should start with the application of a small<br />

amount for a very short time. The surface<br />

being tested should be allowed to dry<br />

completely before judging the full impact of<br />

cleaning. If there is no unfavourable reaction,<br />

longer times and larger amounts can be tried.<br />

If a test clean proves satisfactory in one area,<br />

several other small areas should also be tested<br />

to ensure uniformity of the result before<br />

committing to a course of action.<br />

Ultraviolet light may highlight the degree of<br />

change caused by the cleaning test. For<br />

example, a brightly autofluorescing cleaned<br />

test area may contrast with muted fluorescence<br />

from the untreated coating. This suggests that<br />

non-fluorescing dirt, oil and grime have been<br />

removed and the naturally autofluorescent<br />

coating below has been retained and revealed<br />

through the cleaning process. Conversely, a<br />

total lack of autofluorescence in the test area<br />

may suggest that a coating has been removed<br />

rather than enhanced.<br />

The basic principle behind all cleaning is to<br />

start with the least potentially damaging material<br />

or technique. If ‘stronger’ solvents or<br />

combinations are necessary, tests should<br />

progress in measured increments. Solvents<br />

may be combined with other cleaning<br />

methods or techniques, for example using dry<br />

cleaning materials in combination with hydrocarbon<br />

solvents. The wetting and cleaning<br />

properties of organic solvents may be<br />

enhanced by the addition of a small amount<br />

of a compatible detergent or surfactant.<br />

11.1.6 Dirt<br />

Dirt may be undesirable because it obscures<br />

the aesthetic, informational or other properties<br />

of an object, or accelerates the process of<br />

deterioration. Dirt is generally hygroscopic,<br />

often mildly acidic and may be characterized<br />

by source, size, chemical composition, or the<br />

mechanism by which it adheres to a surface.<br />

Principles of cleaning 499<br />

Air filtered from urban environments may<br />

contain material such as industrial pollutants,<br />

brick dust, salts, oils, waxes, clay, protein, lint,<br />

pollen, mould spores and human skin. Surface<br />

dirt on decorative objects has been characterized<br />

as a combination of particulate material<br />

and greasy or oily material (Phenix and<br />

Burnstock, 1992). The particulate material<br />

varies in chemical composition, surface characteristics,<br />

size, shape and hardness and may<br />

include inorganic material and elemental<br />

carbon. Particles may be present in a range of<br />

sizes but are generally so finely divided that<br />

they exhibit colloidal properties. Carbon black<br />

and other solid particles can attract and absorb<br />

acid and alkaline agents, and oxidizing and<br />

reducing agents, from the surrounding atmosphere.<br />

This absorption can result in the formation<br />

of acid solutions where moisture is<br />

present and promote hydrolytic, oxidative or<br />

reductive breakdown of sensitive materials.<br />

Dirt that contains metal ions has a catalytic<br />

effect on the deterioration of some materials.<br />

Greasy or oily material composed of hydrocarbons<br />

and fats may contain free acids and<br />

also assist the adhesion of particulate matter<br />

to the surface. Dirt is discussed further in<br />

Chapter 6.<br />

Surface grime may be a result of historical<br />

use and such dirt may have value in assisting<br />

in the interpretation of the object. Dirt can be<br />

separated into that which has been deposited<br />

on the object and that which is a result of the<br />

object’s own degradation processes. To<br />

remove the latter is to take away some aspect<br />

of the object’s original material and it is therefore<br />

essential to consider the nature of the<br />

object and how its surface relates to its history<br />

before any cleaning is undertaken.<br />

The probability that dirt will be removed by<br />

a cleaning treatment depends on the type and<br />

strength of the adhesion between dirt and the<br />

surface of the object. Dirt may adhere to a<br />

surface coating mechanically by physical<br />

entrapment, as a result of static electricity, by<br />

hydrogen or dipole bonding or by van der<br />

Waals forces (Moncrieff and Weaver, 1992). It<br />

is usually a combination of these forces that<br />

results in dirt accumulating and remaining on<br />

a surface. The particle size of the dirt also<br />

affects how it is fixed to the surface. Larger<br />

particles of dirt (>1 μm) are held to a surface<br />

largely with electrostatic forces and can be

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