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Series editors' preface - Wood Tools

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The principles outlined above for supporting<br />

tears may be applied to loose areas and lifting<br />

edges. Losses may be infilled using parchment<br />

matched to the colour, texture and surface<br />

treatment of the original. The patch should be<br />

supported using the technique described<br />

above. In some cases it may be appropriate to<br />

laminate new parchment for full support,<br />

though this should be undertaken by an experienced<br />

specialist.<br />

Coatings<br />

Any coating which is applied to previously<br />

untreated parchment will change its appearance,<br />

texture and patina and there is, therefore,<br />

a general presumption against such treatments.<br />

Where parchment has been varnished in the<br />

past there may be areas where the substrate<br />

parchment is exposed. In such cases, the application<br />

of a coating runs the risk of differential<br />

take-up between varnished and unvarnished<br />

areas.<br />

16.4.3 Shagreen<br />

In furniture conservation, the term shagreen<br />

usually refers to the skins of sharks and rays.<br />

The term shagreen is derived from an entirely<br />

different material, sometimes known as ‘shagreen<br />

leather’, derived from the back of a<br />

horse or donkey and embossed with seeds.<br />

The historical derivation of the term can cause<br />

some confusion and it is important to identify<br />

which material is actually present on an object.<br />

The physical characteristic that produces the<br />

decorative effect on ray skins is the presence<br />

of cartillagenous nodules in the grain surface<br />

of the skin. These nodules are hard and the<br />

skins have been used as an abrasive material<br />

in the past. The skin itself could be processed<br />

and abraded to reveal the small white circular<br />

pattern which is characteristic of this material<br />

and produced a hard wearing and decorative<br />

surface. Gopfrich (1999) describes the history<br />

and conservation of shagreen leather, specifically<br />

an untanned hide that had been<br />

embossed with seeds.<br />

The skin of other aquatic animals such as<br />

chat (Squalus catalus) and dogfish have also<br />

been used and are often also called shagreen.<br />

Kite (forthcoming) mentions the use of<br />

untanned shagreen to bind European ceremonial<br />

sword hilts and its incorporation into the<br />

Conserving other materials II 739<br />

handles of Samurai swords and dirks during<br />

the Edo period in Japan (1615–1868). When<br />

used in this way the surface of the shagreen<br />

was not abraded, as the nodules on the skin<br />

provided additional grip.<br />

Shagreen was used in Europe, from the seventeenth<br />

century onwards, as a decorative covering<br />

material for boxes and was also utilized<br />

in instrument cases and jewellery (Willemsen,<br />

1997). The French cabinetmaker Ruhlman often<br />

used shagreen to great decorative effect and<br />

this material enjoyed a period of popularity in<br />

England in the 1920s when it was favoured by<br />

the Duke of Windsor (Springer, 1984).<br />

Both tanned and untanned shagreen may be<br />

encountered as a decorative surface. Although<br />

tanning raises the shrinkage temperature of<br />

leather, in many cases the shagreen used on<br />

articles of furniture was untanned. Although<br />

dry heat is usually tolerated, it may be helpful<br />

to establish the shrinkage temperature before<br />

undertaking a conservation treatment that utilizes<br />

heat, e.g. heat setting of adhesives. The<br />

sudden contraction of the skin at the shrinkage<br />

temperature usually requires both heat and<br />

moisture, but it is possible, for example if<br />

aqueous adhesives have been used, or in conditions<br />

of high ambient RH, or if the shagreen<br />

has been humidified and has not yet returned<br />

to equilibrium with the ambient environment,<br />

for contraction to occur without additional<br />

moisture.<br />

Shrinkage temperature may be established<br />

by taking a small sample, which is thoroughly<br />

soaked in cold water overnight. The temperature<br />

of the water is then raised, ideally at 2 °C<br />

per minute, and the temperature at which the<br />

sample suddenly and irreversibly shrinks is<br />

noted. Microscopic examination using a heated<br />

stage may allow the use of a very small sample<br />

and has been described by Young (1990)<br />

and Larsen et al. (1993). If taking a sample to<br />

establish shrinkage temperature is impracticable<br />

it should be assumed that untanned shagreen<br />

has been used.<br />

The shrinkage temperature of fish collagen is<br />

significantly lower than that of mammalian collagen<br />

(c.65 °C). Generally speaking, the shrinkage<br />

temperature of cold water species is<br />

around 38–45 °C, whilst that of warm water<br />

species is around 50–56 °C. Shrinkage temperature<br />

has a direct relationship with the hydroxyproline<br />

content of the collagen – low

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