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Series editors' preface - Wood Tools

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442 Conservation of Furniture<br />

5%, the wood will rapidly absorb most of the<br />

water from the adhesive. This may result in<br />

glue line starvation and subsequent joint failure.<br />

As a result of the anatomy of wood and its<br />

fibrous nature, wood surfaces are inevitably<br />

rough. This may be compounded by the type<br />

of tooling used in timber preparation. A surface<br />

that has been prepared by a sharp plane or<br />

chisel is characterized by cleanly severed fibres<br />

and minimal dust contamination, whereas<br />

sawn or sanded surfaces result in torn or<br />

crushed fibres and dusty surfaces. Since a<br />

strong adhesive joint requires the least<br />

damaged surface, a planed surface is preferable<br />

to a sanded one. If sanding is unavoidable,<br />

then a finely sanded surface is preferable<br />

to a coarsely sanded surface. Deliberate roughening<br />

the surface, for example by toothing or<br />

scoring the wood, damages the fibres and<br />

creates voids that the adhesive must then fill.<br />

Adhesives traditionally used for veneering,<br />

such as hydrogen bonded animal/hide glue,<br />

have poor gap-filling properties, so this treatment<br />

may result in a weaker adhesive interface<br />

than would have resulted if the surfaces had<br />

been planed smooth. Adhesive penetration in<br />

hardwoods may be limited to one or two fibres<br />

deep, and the resulting adhesive joint may be<br />

compromised if these fibres have been<br />

damaged in the process of preparing the<br />

wood.<br />

The gap-filling properties of an adhesive are<br />

determined by its cohesive strength, which in<br />

turn is dependent on the strength and type of<br />

intermolecular bonding. Adhesives that form a<br />

covalently crosslinked three-dimensional<br />

network within their bulk, such as epoxides<br />

and formaldehyde based glues, have sufficient<br />

cohesive strength to act as gap fillers. All the<br />

solids present are involved in bond formation,<br />

which results in minimal shrinkage on curing.<br />

The adhesive layer may be brittle as a result of<br />

crosslinking holding the molecules rigidly in<br />

place (Skeist, 1962). Gap-filling glues are<br />

unsuitable for many applications in cabinetmaking.<br />

In chair joints, for example, brittleness<br />

caused by the fixed crosslinked bonds means<br />

the adhesive cannot flex when the furniture is<br />

in use, the glue is liable to fracture and the<br />

adhesive fails. Adhesives that do not crosslink,<br />

such as animal/hide glue, are held together by<br />

secondary bonding only and are poor gap<br />

fillers as a result. In order to form a strong<br />

adhesive bond the glue line for such adhesives<br />

must be as thin as possible – typically a maximum<br />

of 0.1 mm for joints in cabinetmaking<br />

(Tout, 1992). Thus the adhesive used in structural<br />

joints in furniture will be most durable<br />

when the joint is close-fitting and the adhesive<br />

has a degree of flexibility in use.<br />

10.1.8 Selecting an adhesive<br />

The material properties of adhesives are<br />

discussed in Chapter 4. The factors involved in<br />

selecting a suitable adhesive may include the<br />

following: the degree of surface preparation<br />

required, viscosity, bond strength, the loads<br />

and stresses that will be placed on the joint,<br />

durability in service in relation to relative<br />

humidity and temperature, retreatability or<br />

reversibility, open time, closed time, toxicity or<br />

other health hazards, characteristics of cured<br />

material, colour, chemical stability, water resistance,<br />

gap-filling ability, formulation, the<br />

nature of the substrate and the cost of the<br />

adhesive product. Adhesives that cure partially<br />

or wholly by loss of a volatile solvent, such as<br />

PVACs and animal/hide glue, are prone to<br />

shrinkage during curing although thin glue<br />

lines will minimize the resultant stress in the<br />

cured glue line. The effect of adding fillers to<br />

collagen glue has been examined by Von Endt<br />

and Baker (1991).<br />

Animal/hide glue has proven to be very<br />

effective and continues to be used by the<br />

majority of furniture conservators for structural<br />

repairs. It should be freshly made and can be<br />

kept for several weeks provided that it is refrigerated.<br />

The protein chains slowly break down<br />

each time the glue is heated, especially when<br />

it is overheated, which reduces the strength of<br />

the glue. Whilst large restoration workshops<br />

may keep a continuous supply of hot<br />

animal/hide glue to hand, if use is intermittent<br />

it is better to make small fresh batches as<br />

required.<br />

Although animal/hide glue is a poor gap<br />

filler, freshly prepared glue will provide an<br />

adhesive bond comparable in strength to an<br />

epoxy. It is usually sold in the form of pearls,<br />

which should be covered with water and presoaked<br />

overnight then warmed the following<br />

day at 55–60 °C. Water is added as necessary<br />

to produce the right working consistency,

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