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Series editors' preface - Wood Tools

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ecoming progressively harder and darker (see<br />

Mills and White (1994) for a description of the<br />

oxidation of drying oils). Dirt may become<br />

incorporated into the film structure as it<br />

crosslinks. Coatings with a significant oil<br />

content are sensitive to, and may be damaged<br />

by, aqueous solutions with a pH higher than<br />

8.5, bases, polar organic and chlorinated<br />

solvents. Water may be used to clean an oil<br />

finish if it is applied sparingly on a damp swab<br />

or cloth and the surfaced is wiped immediately<br />

with a dry cloth. Although original intent<br />

should be a consideration in selecting a treatment,<br />

maintaining an oil finish with wax may<br />

be preferable to an irreversible re-oiling treatment.<br />

Resinous coatings, e.g. sandarac or shellac,<br />

may appear matte, semi-matte or highly glossy<br />

depending on age and the use of matting<br />

agents or others dulling treatments. They are<br />

auto-fluorescent under UV, though the colour<br />

of the fluorescence varies according to the<br />

resin type/s and the age of the coating. Aged<br />

resinous coatings are usually insoluble in<br />

hydrocarbon solvents but may be dissolved by<br />

alcohols and ketones. In addition, resinous<br />

coatings are generally sensitive to elevated pH<br />

and polar organic solvents. The removal of dirt<br />

from natural resin varnishes that are in good<br />

condition is usually straightforward (Figure<br />

13.2). Wax or greasy accretions may be<br />

removed with a swab dampened with an<br />

aliphatic or aromatic hydrocarbon solvent. It<br />

should be noted that these solvents will<br />

remove some synthetic resins. Cleaning may<br />

utilize a swab or cloth dampened with water<br />

followed immediately by wiping over with a<br />

soft dry cloth. Aqueous cleaning of resinous<br />

transparent coatings requires some care as the<br />

water molecules may diffuse into the coating<br />

and cause blooming. The risk of bloom<br />

increases with the degree of ageing of the<br />

varnish, exposure time and as the pH of the<br />

cleaning solution rises. Some very degraded<br />

natural resin surfaces may be partially soluble<br />

in water with a pH of only 8–8.5, a fact that<br />

has been exploited in varnish removal treatments<br />

(Wolbers et al., 1990). The principles of<br />

aqueous cleaning are discussed in section<br />

11.5. Blooming of resinous coatings is also<br />

often associated with long exposure to<br />

moisture or a combination of heat and<br />

moisture, for example if excess warmed<br />

Conserving transparent coatings on wood 609<br />

(a) (b)<br />

Figure 13.2 Scanning electron microscopy (SEM)<br />

photomicrographs of an aged natural resin varnish<br />

(a) Before cleaning: accretions darken and obscure the<br />

mahogany substrate. (b) After cleaning: accretions have<br />

been removed and the original varnish remains intact<br />

animal glue used to repair the wood substrate<br />

is left in contact with the varnished surface<br />

when the repair is cramped up.<br />

Oleo-resinous varnishes were often<br />

employed where a hard-wearing surface was<br />

required and are particularly associated with<br />

the nineteenth century. Drying oils such as<br />

linseed or tung oil were used in combination<br />

with natural resins such as sandarac, mastic or<br />

gum elemi, with fossil resins such as copal or<br />

amber, or in combinations of these materials<br />

with the addition of colophony.<br />

Limed finishes were created by scrubbing the<br />

surface of an open-grained timber such as oak<br />

or ash to accentuate and open the large pores<br />

associated with early seasonal growth.<br />

Traditionally, quick lime (calcium oxide) was<br />

dissolved in an equivalent quantity of water to<br />

produce highly alkaline slaked lime (calcium<br />

hydroxide). A thick mixture was rubbed into<br />

the surface of the wood and lodged in the large<br />

opened pores of the early wood. Excess was<br />

removed from the surface and the lime that<br />

remained in the pores created a striking decorative<br />

effect. The alkaline liming treatment may<br />

have had the additional purpose of disinfecting

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