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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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80 <strong>George</strong> <strong>Wypych</strong><br />

Property<br />

minimum<br />

Value<br />

maximum median<br />

vapor pressure, kPa 0.01 11.0 2.62<br />

viscosity, mPa.s 0.34 1.96 0.77<br />

dissociation constant, pKa 7.67 10.21 8.98<br />

donor number, DN, kcal/mol 4.4 16.6 11.0<br />

acceptor number, AN 14.8 20.5 17.7<br />

polarity parameter, ET(30), kcal/mol 41.5 46.7 43.6<br />

heat <strong>of</strong> combustion, MJ/kg 22.46 30.38 27.25<br />

Hildebrand solubility parameter, cal 1/2 cm -3/2<br />

9.5 12.3 10.5<br />

evaporation rate (butyl acetate = 1) 1.15 2.3 2.1<br />

threshold limiting value - 8h average, ppm 1 100 25<br />

LD50 oral, mg/kg 39 3800 510<br />

route <strong>of</strong> entry absorption, contact. ingestion, inhalation<br />

target organs<br />

blood, central nervous system, eye, kidney, liver,<br />

respiratory system, skin<br />

carcinogenicity acrylonitrile, 2-nitropropane<br />

mutagenic properties acrylonitrile, 2-nitropropane<br />

biodegradation probability days-weeks<br />

octanol/water partition coefficient -0.3 1.86<br />

3.3.4 ORGANIC SULFUR COMPOUNDS<br />

Property<br />

minimum<br />

Value<br />

maximum median<br />

boiling temperature, o C 37 287 142<br />

freezing temperature, o C -116 32 -38<br />

flash point, o C -38 177 43<br />

autoignition temperature, o C 206 470 395<br />

refractive index 1.38 1.62 1.47<br />

specific gravity, g/cm 3<br />

0.80 1.43 1.00<br />

vapor density (air=1) 2.14 4.35 3.05<br />

vapor pressure, kPa 0.00 19.00 1.05<br />

viscosity, mPa.s 0.28 10.29 0.97<br />

surface tension, mN/m 35.5 42.98 39.00

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