Handbook of Solvents - George Wypych - ChemTech - Ventech!

110 Valery Yu. Senichev, Vasiliy V. Tereshatov
Solvent
V1,
Kmol/m 3
δ,
(MJ/m 3 ) 1/2
δd,
(MJ/m 3 ) 1/2
δp,
(MJ/m 3 ) 1/2
δh,
(MJ/m 3 ) 1/2
1-Pentanol 108.3 21.6 15.9 4.5 13.9
Benzyl alcohol 103.6 24.8 18.4 6.3 13.7
Cyclohexanol 106.0 23.3 17.3 4.1 13.5
Ethylene glycol
monomethyl ether
79.1 23.3 16.2 9.2 16.4
Ethylene glycol
monoethyl ether
97.8 21.5 16.2 9.2 14.3
Ethylene glycol
monobutyl ether
142.1 20.8 15.9 4.5 12.7
1-Octanol 157.7 21.1 17.0 3.3 11.9
m-Cresol 104.7 22.7
Carboxylic acids
18.0 5.1 12.9
Formic acid 37.8 24.8 14.3 11.9 16.6
Acetic acid 57.1 20.7 14.5 8.0 13.5
n-Butyric acid 110 21.5
Polyhydric alcohols
14.9 4.1 10.6
Ethylene glycol 55.8 33.2 16.8 11.0 25.9
Glycerol 73.3 43.8 17.3 12.0 29.2
Diethylene glycol 95.3 29.8 16.0 14.7 20.4
Triethylene glycol 114.0 21.9 16.0 12.5 18.6
Water 18.0 47.9 15.5 16.0 42.3
4.1.3 MULTI-DIMENSIONAL APPROACHES
These approaches can be divided into three types:
1 H-bonds are not considered. This approach can be applied only for
nonpolar and weak polar liquids.
2 H-bonds taken into account by one parameter.
3 H-bonds taken into account by two parameters.
Blanks and Prausnitz 8,9 proposed two-component solubility parameters. They decomposed
the cohesion energy into two contributions of polar and non-polar components:
where:
E E nonpolar E polar 2 2
− =− − = λ + τ [4.1.15]
V V V
1 1 1
λ non-polar contribution to solubility parameter
τ polar contribution to solubility parameter