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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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92 <strong>George</strong> <strong>Wypych</strong><br />

Property<br />

minimum<br />

Value<br />

maximum median<br />

dielectric constant 2.42 37.78 29.36<br />

Hildebrand solubility parameter, cal 1/2 cm -3/2<br />

7.4 15.5 10.5<br />

Henry’s Law constant, atm/m 3 mol 1.7E-23 3.38E+1 1.56E-8<br />

evaporation rate (butyl acetate = 1) 0.001 3.59 0.06<br />

threshold limiting value - 8h average, ppm 0.1 100 5<br />

maximum concentration (15 min exp), ppm 6 35 15<br />

maximum concentration any time, ppm 5<br />

LD50 oral, mg/kg 100 12760 470<br />

LD50 dermal, mg/kg 64 8000 660<br />

route <strong>of</strong> entry absorption, contact. ingestion, inhalation<br />

target organs<br />

carcinogenicity<br />

mutagenic properties<br />

eye, kidney, lymphatic system, liver, lung, respiratory<br />

system, skin, testes<br />

acetamide, p-chloroaniline, N,N-dimethylformamide,<br />

hydrazine, N-nitrosodimethylamine, o-toluidyne<br />

dimethylamine, ethylene diamine tetracetic acid,<br />

methylamine, N-methylpyrrolidone, N-nitrosomethyl<br />

amine, tetraethylene pentamine<br />

biological oxygen demand, 5-day test, g/g 0.01 2.24 0.84<br />

chemical oxygen demand, g/g 1.28 1.9 1.53<br />

theoretical oxygen demand, g/g 0.65 2.85 1.8<br />

biodegradation probability days-weeks<br />

octanol/water partition coefficient -1.66 1.92<br />

urban ozone formation 0.00 0.51 0.21<br />

3.3.13 ESTERS<br />

Property<br />

minimum<br />

Value<br />

maximum median<br />

boiling temperature, o C 32 343 165<br />

freezing temperature, o C -148 27.5 -54<br />

flash point, o C -19 240 64<br />

autoignition temperature, o C 252 505 400<br />

refractive index 1.34 1.56 1.44<br />

specific gravity, g/cm 3<br />

0.81 1.38 0.92

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