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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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14.15 Medical applications 955<br />

Solventborne wood preservatives contain mainly nonpolar, organic solvents apart<br />

from other substances such as fungicides and insecticides. 1 These solvents are classified as<br />

VOCs.<br />

14.14.2.2 Technical and environmental aspects<br />

Solvent-based wood preservatives show several advantages, especially in their application<br />

and technical effectiveness. 1 They can be applied repeatedly and do not alter the structure <strong>of</strong><br />

the wood products. Application is faster and the characteristics <strong>of</strong> the final product are improved,<br />

e.g., visual appearance <strong>of</strong> surface.<br />

Nevertheless, there are some disadvantages, especially environmental ones. Most solvents<br />

are released quickly (VOCs) and can cause severe environmental effects. This is especially<br />

true if toxic solvents are employed.<br />

Emissions <strong>of</strong> solvents from wood products are described under various conditions,<br />

e.g. indoor air emissions from furniture or emissions in test chambers. 3,4 <strong>Solvents</strong> can be<br />

emitted as primary or reactive products <strong>of</strong> the wood product or the coating system; solvents<br />

can also be investigated as secondary emission products. 3,5 The emission characteristics depend<br />

on solvent properties and surrounding conditions, e.g., air velocity and air exchange<br />

rate. 6<br />

In the indoor air, solvents from wood products follow various pathways. Examples <strong>of</strong><br />

interactions are possible reactions <strong>of</strong> solvents (e.g., styrene) with air components (e.g.,<br />

hydroxy radicals), 3 transport into and through indoor materials 7 or sorption processes. 5 The<br />

emitted solvents can be reduced by ventilation processes or they may be absorbed by organisms.<br />

For humans, absorption <strong>of</strong> the wood preservatives or ingredients (e.g., solvents) can<br />

cause various toxic effects. It is <strong>of</strong>ten difficult to pinpoint the causative agents (see Chapter<br />

20).<br />

REFERENCES<br />

1 Ullmann`s Encyclopedia <strong>of</strong> Industrial Chemistry, 1998.<br />

2 DIBt (Deutsches Institut für Bautechnik). Holzschutzmittelverzeichnis. Index <strong>of</strong> wood preservatives (1999).<br />

3 T. Salthammer, A. Schwarz, F. Fuhrmann, Atmospher. Environ., 33, 75 (1999).<br />

4 T. Salthammer, Atmospher. Environ., 7, 189 (1997).<br />

5 M. Wensing, H.J. Moriske, T. Salthammer, Gefahrst<strong>of</strong>fe Reinhaltung der Luft, 58, 463 (1998).<br />

6 E. Uhde, A. Borgschulte, T. Salthammer, Atmospher. Environ., 32, 773 (1998).<br />

7 R. Meininghaus, T. Salthammer, H. Knoppel, Atmospher. Environ., 33, 2395 (1999).<br />

14.15 MEDICAL APPLICATIONS<br />

<strong>George</strong> <strong>Wypych</strong><br />

ChemTec Laboratories, Inc., Toronto, Canada<br />

Industries manufacturing medical devices use a wide variety <strong>of</strong> technological processes<br />

which most likely take advantage <strong>of</strong> most <strong>of</strong> the available solvents. The range <strong>of</strong> solvent use<br />

is so wide that a complete description <strong>of</strong> each solvent and its application is not possible in<br />

this book. It is questionable if such analysis is possible given that many processes are<br />

guarded by trade secrets where there is no patent disclosure. Some examples are given,

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