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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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3.3 Solvent properties 85<br />

Property<br />

minimum<br />

Value<br />

maximum median<br />

target organs<br />

central nervous system, eye, respiratory system,<br />

skin<br />

carcinogenicity 3-chlorophenol, o-chlorophenol<br />

mutagenic properties 3-chlorophenol, o-chlorophenol<br />

octanol/water partition coefficient 0.59 2.47<br />

3.3.8 ALDEHYDES<br />

Property<br />

minimum<br />

Value<br />

maximum median<br />

boiling temperature, o C -21 253 162<br />

freezing temperature, o C -123 12.4 -86<br />

flash point, o C -39 102 13<br />

autoignition temperature, o C 180 424 196<br />

refractive index 1.33 1.62 1.44<br />

specific gravity, g/cm 3<br />

0.70 1.25 0.85<br />

vapor density (air=1) 1 4.5 2.5<br />

vapor pressure, kPa 0.00 438 2.30<br />

viscosity, mPa.s 0.32 5.4 1.32<br />

surface tension, mN/m 23.14 41.1 32.00<br />

donor number, DN, kcal/mol 16<br />

acceptor number, AN 12.8<br />

heat <strong>of</strong> vaporization, cal/g 5.53 10.33 6.77<br />

Hildebrand solubility parameter, cal 1/2 cm -3/2<br />

8.33 11.7 10.85<br />

evaporation rate (butyl acetate = 1) 7.8<br />

threshold limiting value - 8h average, ppm 0.1 100 2<br />

maximum concentration (15 min exp), ppm 0.3 150<br />

maximum concentration any time, ppm 0.2 0.3<br />

LD50 oral, mg/kg 46 3078 100<br />

LD50 dermal, mg/kg 270 16000 582<br />

route <strong>of</strong> entry absorption, contact. ingestion, inhalation<br />

target organs eye, heart, liver, respiratory system, skin<br />

carcinogenicity acetaldehyde, formaldehyde, furfural

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