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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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23.1 Natural attenuation <strong>of</strong> chlorinated solvents 1585<br />

against the other hydrogen utilizers for the available hydrogen. Smatlak et al. 51 suggest that<br />

the competition for hydrogen is controlled primarily by the Monod half-saturation constant<br />

Ks(H2), the concentration at which a specific strain <strong>of</strong> bacteria can utilize hydrogen at half<br />

the maximum utilization rate. Ballapragada et al., 52 however, provide a more detailed discussion<br />

<strong>of</strong> halorespiration kinetics and point out that competition for hydrogen also depends<br />

on additional factors including the bacterial growth rate and maximum hydrogen utilization<br />

rate.<br />

Smatlak et al. 51 have suggested that the steady-state concentration <strong>of</strong> hydrogen will be<br />

controlled by the rate <strong>of</strong> hydrogen production from fermentation. Both laboratory results<br />

and field observations have suggested, however, that the steady-state concentration <strong>of</strong> hydrogen<br />

is controlled by the type <strong>of</strong> bacteria utilizing the hydrogen and is almost completely<br />

independent <strong>of</strong> the rate <strong>of</strong> hydrogen production. 52,55-57 Under nitrate reducing conditions,<br />

steady-state H2 concentrations were

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