Handbook of Solvents - George Wypych - ChemTech - Ventech!

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14.19.1 Architectural surface coatings 965 The following are examples of architectural surface coatings. 14.19.1.2.1 Concrete coating materials According to DIN 1045 concrete must be protected against aggressive substances if the chemical attack is severe and long-term. These are the requirements: • Good adhesion • Waterproof and resistant to aggressive substances and resistant to the alkalinity of the concrete • Deformable To realize these requirements, the following technical solutions can be applied: • The use of paint coatings based on duroplast or thermoplastic substances • Surface treatment - impregnation Protective coatings based on polymers are used in construction with and without fillers and with or without reinforcing materials (fibers). The following techniques are generally used: • Film forming paint coatings (brushing, rolling, spraying). • Coating (filling, pouring). During application, the coating materials are normally liquid and subsequently harden by evaporation of solvents or as a result of chemical reactions. The common coating systems for concrete are listed in Table 14.19.1.2. Synthetic resins (e.g., chlorinated rubber, styrene resins, acrylic resins) contain normally 40-60% solvents and form a thin film. Several coats must be applied. Reactive resins may require little or no solvent. Table 14.19.1.2. Survey of often used coating systems for concrete Film-forming agents Hotmelts Film-forming agents dissolved Film-forming agents emulsified Reaction resin liquid Bituminous substances + + + Synthetic resin + + Reactive resins (+) (+) + 14.19.1.2.2 Coating materials for metals Wet coating processes are detailed in Table 14.19.1.3.
966 Tilman Hahn, Konrad Botzenhart, Fritz Schweinsberg, Gerhard Volland Table 14.19.1.3. Wet coatings - coating materials for metals Natural substances Plastic materials Abbreviation Application State Curing method oil OEL oxidizing bitumen B binders for wet coating physical tar T physical alkyd resin AK oxidizing polyurethane epoxy resin PU EP liquid chemical chemical acrylic resin AY binders for wet coating physical vinyl resin PVC physical chlorinated rubber RUC physical The chemical properties of binders are not affected by the drying process if coatings are of physically drying type. After solvent has evaporated, the polymer molecules become intermeshed, thus producing the desired coating properties. In contrast to physical drying, binders based on reactive resins such as epoxy resins, polyurethanes or polyesters consist of two components (liquid resin and curing agent) which are either mixed shortly before the coat is applied, or, in the case of a one component system, one which is applied as slow reacting mixture. The setting reaction occurs at the surface of the coated material. The final products are normally more resistant and more compact than products based on physically drying binders. Pretreatment of substrate is more critical for applications where chemically hardening products are applied. Coatings can be more or less permeable to water vapor and oxygen. Damage to the metal substrate can occur if water and oxygen reach the reactive surface simultaneously. This is normally impossible if the coatings adhere well and the coated surface is continuous. The adhesion of the coating also prevents the penetration by harmful substances via diffusion processes. Adhesion is enhanced by adsorption and chemical bonds. 14.19.1.2.3 Other coating materials Other aspects of solvents contained in paint coatings and varnishes are given in Chapter 18.3. The market offers a wide spectrum of coating systems. Examples of common industrial coating materials are listed in Table 14.19.1.4 and relevant aspects concerning application and environmental or health risks are also included.
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HANDBOOK OF SOLVENTS George Wypych,
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Preface Although the chemical indus
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Preface xxix contain or to have use
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1654 Acknowledgments 10.3 Solvent e
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Table of Contents Preface .........
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Table of contents iii 4.3 Polar sol
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Table of contents v 7.2.1.1 Rheolog
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Table of contents vii 9.4.4 Solvent
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Table of contents ix 12.2.2.1 Chemi
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Table of contents xi 14.4.3.1 Intro
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Table of contents xiii 14.19 Paints
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Table of contents xv 15.1.20 Gas ch
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Table of contents xvii 17.2.2 Movem
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Table of contents xix 18.4.7 Dry cl
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Table of contents xxi 20.7.1 Introd
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Table of contents xxiii 21.4.1.3 Pr
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Table of contents xxv 23.2.1.3 Sour
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2 Christian Reichardt aliphatic nit
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4 Christian Reichardt the knowledge
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2 Fundamental Principles Governing
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2.1 Solvent effects on chemical sys
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2.2 Molecular design of solvents 37
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2.3 Basic physical and chemical pro
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66 George Wypych Aprotic/Protic Ter
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68 George Wypych Biodegradability T
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70 George Wypych Figure 3.2.1. Sche
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72 George Wypych Figure 3.3.4. Simp
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74 George Wypych Synthetic routes a
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76 George Wypych Property minimum V
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96 Tilman Hahn, Konrad Botzenhart,
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98 Tilman Hahn, Konrad Botzenhart,
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General Principles Governing Dissol
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4.1 Simple solvent characteristics
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4.2 Effect of system variables on s
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4.3 Polar solvation dynamics 133 tr
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4.3 Polar solvation dynamics 135 Fo
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4.3 Polar solvation dynamics 137 at
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4.3 Polar solvation dynamics 139 li
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4.3 Polar solvation dynamics 141 Fi
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4.3 Polar solvation dynamics 143 Fi
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4.3 Polar solvation dynamics 145 ta
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4.4 Measurement of solvent activity
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Solubility of Selected Systems and
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5.1 Solubility parameters 245 ln P
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5.1 Solubility parameters 247 Accep
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5.1 Solubility parameters 249 media
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5.1 Solubility parameters 251 Polym
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5.2 Prediction of solubility parame
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5.3 Methods of calculation of solub
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5.4 Mixed solvents - polymer solubi
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5.5 The phenomenological theory of
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306 E. Ya. Denisyuk, V. V. Tereshat
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318 V V Tereshatov, V Yu. Senichev,
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328 Vasiliy V. Tereshatov, Valery Y
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340 George Wypych where: τM the mo
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342 George Wypych ξ 0.55 0.5 0.45
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344 George Wypych Self-diffusion co
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346 George Wypych Temperature, K 31
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348 George Wypych Diffusion distanc
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350 George Wypych • evaporation-i
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352 George Wypych Water volume frac
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354 George Wypych Diffusion coeffic
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356 Semyon Levitsky, Zinoviy Shulma
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386 Seung Su Kim, Jae Chun Hyun 7.3
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388 Seung Su Kim, Jae Chun Hyun rat
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390 Seung Su Kim, Jae Chun Hyun The
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392 Seung Su Kim, Jae Chun Hyun whe
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394 Seung Su Kim, Jae Chun Hyun beg
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396 Seung Su Kim, Jae Chun Hyun 7.3
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398 Seung Su Kim, Jae Chun Hyun Fig
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404 Seung Su Kim, Jae Chun Hyun sol
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406 Seung Su Kim, Jae Chun Hyun Tab
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408 Seung Su Kim, Jae Chun Hyun and
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410 Seung Su Kim, Jae Chun Hyun to
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412 Seung Su Kim, Jae Chun Hyun The
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414 Seung Su Kim, Jae Chun Hyun cau
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416 Seung Su Kim, Jae Chun Hyun Nu
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Interactions in Solvents and Soluti
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8.2 Basic simplifications of quantu
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8.2 Basic simplifications of quantu
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8.4 Two-body interaction energy 425
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8.5 Three- and many-body interactio
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8.6 The variety of interaction pote
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8.6 The variety of interaction pote
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8.7 Theoretical and computing model
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8.8 Practical applications of model
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8.9 Liquid surfaces 493 to study th
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8.9 Liquid surfaces 495 The potenti
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8.9 Liquid surfaces 497 out of equi
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8.9 Liquid surfaces 499 tions) of t
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8 Interactions in solvents and solu
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8 Interactions in solvents and solu
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9 Mixed Solvents Y. Y. Fialkov, V.
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9.2 Chemical interaction between co
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9.2 Chemical interaction between co
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9.3 Physical properties of mixed so
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9.4 Mixed solvent influence on the
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9.5 The mixed solvent effect on the
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9 Mixed solvents 563 22 Minkin V.,
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10 Acid-base Interactions 10.1 GENE
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10.1 General concept of acid-base i
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10.1 General concept of acid-base i
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10.2 Effect of polymer/solvent acid
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10.3 Solvent effects based on pure
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10.4 Acid-base equilibria in ionic
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11 Electronic and Electrical Effect
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11.1 Theoretical treatment of solve
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11.2 Dielectric solvent effects 681
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12 Other Properties of Solvents, So
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12.1 Rheological properties, aggreg
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12.2 Chain conformations of polysac
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738 Roland Schmid Figure 13.1.1. Re
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740 Roland Schmid HB interactions,
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742 Roland Schmid AN = -133.8 - 0.0
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744 Roland Schmid ated by the macro
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746 Roland Schmid turns out, polar
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748 Roland Schmid Packing density
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750 Roland Schmid tween calculated
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752 Roland Schmid over the solute-s
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754 Roland Schmid of the empirical
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756 Roland Schmid From X-ray and ne
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758 Roland Schmid Table 13.1.5. Sol
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760 Roland Schmid ΔG = ΔG + ΔG [
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762 Roland Schmid very recent paper
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764 Roland Schmid Solvent ΔvH/RT
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766 Roland Schmid E r = E i + E s [
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768 Roland Schmid from the explicit
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770 Roland Schmid sequently, there
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772 Roland Schmid simulations. 188-
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774 Roland Schmid 23 N. A. Lewis, Y
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776 Roland Schmid 132 R. R. Dogonad
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778 Michelle L. Coote and Thomas P.
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798 Maw-Ling Wang 13.3 EFFECTS OF O
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800 Maw-Ling Wang [13.3.2] Inverse
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802 Maw-Ling Wang Both cation and a
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804 Maw-Ling Wang Table 13.3.2. Eff
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806 Maw-Ling Wang Table 13.3.3. Ext
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808 Maw-Ling Wang Table 13.3.5. Eff
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810 Maw-Ling Wang reacts with pheno
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812 Maw-Ling Wang Figure 13.3.3. Ef
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814 Maw-Ling Wang the organic solve
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816 Maw-Ling Wang crease. Therefore
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818 Maw-Ling Wang (F) Polymerizatio
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820 Maw-Ling Wang Table 13.3.16. Sy
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822 Maw-Ling Wang 13.3.1.4 Effect o
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824 Maw-Ling Wang Table 13.3.19 Eff
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826 Maw-Ling Wang quaternary salt c
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828 Maw-Ling Wang Table 13.3.24. Ef
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830 Maw-Ling Wang Solvent Dielectri
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832 Maw-Ling Wang ied. 82,83,97,101
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834 Maw-Ling Wang substitution, suc
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836 Maw-Ling Wang (2) the ion excha
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838 Maw-Ling Wang REFERENCES 1 A. A
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840 Maw-Ling Wang 101 D. C. Sherrin
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842 Norio Tsubokawa [13.4.2] PAI is
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844 Norio Tsubokawa Table 13.4.2. I
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846 Norio Tsubokawa more easily tha
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848 George Wypych methyl amyl keton
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850 George Wypych Peel strength, N/
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852 George Wypych 8 P Enenkel, H Ba
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854 George Wypych Table 14.2.2. Tot
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856 M Matsumoto, S Isken, JAMdeBont
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866 Tilman Hahn, Konrad Botzenhart
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872 Tsuneo Yamane 14.4.3 CHOICE OF
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874 Tsuneo Yamane Very trace amount
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876 Tsuneo Yamane It has been shown
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878 Tsuneo Yamane [ ( kcat Km) ( kc
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880 George Wypych 11 A. Zaks, in En
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882 George Wypych rected towards im
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884 Kaspar D. Hasenclever than 55°
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886 Kaspar D. Hasenclever The same
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888 Kaspar D. Hasenclever Figure 14
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890 Kaspar D. Hasenclever Computer
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892 Kaspar D. Hasenclever • Solve
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894 Martin Hanek, Norbert Löw, And
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1016 George Wypych 72 K. Brololm, a
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1018 George Wypych Figure 14.22.2.
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1020 George Wypych New technology i
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1022 George Wypych Table 14.23.1. R
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1026 Mohamed Serageldin, Dave Reeve
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1050 George Wypych Table 14.32.5. T
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1052 George Wypych The traditional
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1054 George Wypych The acidity of b
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1056 George Wypych except water whi
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1058 George Wypych solution is 2.73
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1060 George Wypych presence of igni
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1062 George Wypych method of determ
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1064 George Wypych used. A thermal
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1066 George Wypych 15.1.26 REFRACTI
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1068 George Wypych Table 15.1.1. Ty
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1070 George Wypych Wexcluded solven
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1072 George Wypych 25 ASTM D 2108-9
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1074 George Wypych 68 ASTM D 3844-9
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1076 George Wypych BS 506-2.84. Met
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1078 Myrto Petreas 15.2 SPECIAL MET
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1080 Myrto Petreas In short, biolog
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1082 Myrto Petreas cients of some i
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1084 Myrto Petreas lection at the a
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1086 Myrto Petreas and legal reperc
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1088 Myrto Petreas • The solvent
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1090 Myrto Petreas of time after ex
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1092 Myrto Petreas even after log-l
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1094 Myrto Petreas 26 M Petreas, J
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1096 James L. Botsford In Europe ma
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1098 James L. Botsford Figure 15.2.
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1100 James L. Botsford cussed. Neit
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1102 James L. Botsford n Ave. Var.
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1104 James L. Botsford (Calleja et
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1106 James L. Botsford Table 15.2.2
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1108 James L. Botsford the test is
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1110 James L. Botsford Table 15.2.2
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1112 James L. Botsford Geiger, D. L
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1114 Christine Barthélémy, Michel
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1126 George Wypych n-heptane molecu
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1128 George Wypych MEK P PA Fat-fre
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1130 Michel Bauer, Christine Barth
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17 Environmental Impact of Solvents
Page 1177 and 1178:
17.1 The environmental fate and mov
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Page 1187 and 1188:
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17.2 Fate-based management 1163 dat
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17.2 Fate-based management 1165 bre
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17.2 Fate-based management 1167 gra
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17.3 Environmental fate of glycol e
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Page 1199 and 1200:
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17.4 Organic solvent impacts on tro
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Page 1223 and 1224:
Page 1225 and 1226:
Page 1227 and 1228:
18 Concentration of Solvents in Var
Page 1229 and 1230:
18.1 Measurement and estimation of
Page 1231 and 1232:
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18.2 Prediction of organic solvents
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18.3 Indoor air pollution by solven
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Page 1267 and 1268:
Page 1269 and 1270:
Page 1271 and 1272:
Page 1273 and 1274:
Page 1275 and 1276:
Page 1277 and 1278:
18.4 Solvent uses with exposure ris
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Page 1291 and 1292:
Page 1293 and 1294:
1268 Carlos M. Nu�ez ter or habit
Page 1295 and 1296:
1270 Carlos M. Nu�ez CAS No. Chem
Page 1297 and 1298:
Page 1299 and 1300:
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Page 1307 and 1308:
1282 Carlos M. Nu�ez tronic circu
Page 1309 and 1310:
1284 Carlos M. Nu�ez EPA Region 6
Page 1311 and 1312:
1286 Carlos M. Nu�ez i.e., entire
Page 1313 and 1314:
1288 Carlos M. Nu�ez Table 19.6.
Page 1315 and 1316:
1290 Carlos M. Nu�ez Schedule Sou
Page 1317 and 1318:
1292 Carlos M. Nu�ez The CAA prov
Page 1319 and 1320:
1294 Carlos M. Nu�ez CWA to estab
Page 1321 and 1322:
1296 Carlos M. Nu�ez amended to i
Page 1323 and 1324:
1298 Carlos M. Nu�ez Figure 19.5.
Page 1325 and 1326:
1300 Carlos M. Nu�ez environmenta
Page 1327 and 1328:
1302 Carlos M. Nu�ez For comparis
Page 1329 and 1330:
1304 Carlos M. Nu�ez tives. Four
Page 1331 and 1332:
1306 Carlos M. Nu�ez • Program
Page 1333 and 1334:
1308 Carlos M. Nu�ez 31 Federal R
Page 1335 and 1336:
1310 Carlos M. Nu�ez HSWA Hazardo
Page 1337 and 1338:
Page 1339 and 1340:
20 Toxic Effects of Solvent Exposur
Page 1341 and 1342:
20.1 Toxicokinetics, toxicodynamics
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Page 1347 and 1348:
Page 1349 and 1350:
Page 1351 and 1352:
20.2 Cognitive and psychosocial out
Page 1353 and 1354:
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Page 1357 and 1358:
20.3 Pregnancy outcome following so
Page 1359 and 1360:
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Page 1369 and 1370:
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Page 1375 and 1376:
Page 1377 and 1378:
Page 1379 and 1380:
20.4 Industrial solvents and kidney
Page 1381 and 1382:
Page 1383 and 1384:
Page 1385 and 1386:
Page 1387 and 1388:
20.5 Lymphohematopoietic study of w
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Page 1395 and 1396:
Page 1397 and 1398:
Page 1399 and 1400:
20.6 Chromosomal aberrations 1375 2
Page 1401 and 1402:
20.6 Chromosomal aberrations 1377 p
Page 1403 and 1404:
20.7 Hepatotoxicity 1379 8 Mitelman
Page 1405 and 1406:
20.7 Hepatotoxicity 1381 to convert
Page 1407 and 1408:
20.7 Hepatotoxicity 1383 Table 20.7
Page 1409 and 1410:
20.7 Hepatotoxicity 1385 toxicity o
Page 1411 and 1412:
20.7 Hepatotoxicity 1387 early pote
Page 1413 and 1414:
20.7 Hepatotoxicity 1389 vents. It
Page 1415 and 1416:
20.7 Hepatotoxicity 1391 19 Slater
Page 1417 and 1418:
20.8 Solvents and the liver 1393 20
Page 1419 and 1420:
20.8 Solvents and the liver 1395 Cu
Page 1421 and 1422:
20.8 Solvents and the liver 1397 th
Page 1423 and 1424:
20.8 Solvents and the liver 1399 cu
Page 1425 and 1426:
Page 1427 and 1428:
Page 1429 and 1430:
20.9 Toxicity of environmental solv
Page 1431 and 1432:
Page 1433 and 1434:
Page 1435 and 1436:
Page 1437 and 1438:
Page 1439 and 1440:
Page 1441 and 1442:
Page 1443 and 1444:
21 Substitution of Solvents by Safe
Page 1445 and 1446:
21.1 Supercritical solvents 1421 So
Page 1447 and 1448:
21.1 Supercritical solvents 1423 Fi
Page 1449 and 1450:
Page 1451 and 1452:
Page 1453 and 1454:
21.1 Supercritical solvents 1429 K
Page 1455 and 1456:
21.1 Supercritical solvents 1431 ai
Page 1457 and 1458:
21.1 Supercritical solvents 1433 Th
Page 1459 and 1460:
21.1 Supercritical solvents 1435 wh
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21.1 Supercritical solvents 1437 *
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21.1 Supercritical solvents 1439 In
Page 1465 and 1466:
21.1 Supercritical solvents 1441 21
Page 1467 and 1468:
21.1 Supercritical solvents 1443 Ta
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21.1 Supercritical solvents 1445 Re
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21.1 Supercritical solvents 1447 Re
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21.1 Supercritical solvents 1449 ta
Page 1475 and 1476:
Page 1477 and 1478:
Page 1479 and 1480:
Page 1481 and 1482:
Page 1483 and 1484:
21.2 Ionic liquids 1459 85 M. Polia
Page 1485 and 1486:
21.2 Ionic liquids 1461 be used. Th
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21.2 Ionic liquids 1463 Figure 21.2
Page 1489 and 1490:
21.2 Ionic liquids 1465 Table 21.2.
Page 1491 and 1492:
21.2 Ionic liquids 1467 been utiliz
Page 1493 and 1494:
21.2 Ionic liquids 1469 One specifi
Page 1495 and 1496:
21.2 Ionic liquids 1471 lustrates t
Page 1497 and 1498:
21.2 Ionic liquids 1473 these alloy
Page 1499 and 1500:
21.2 Ionic liquids 1475 ( ) ln = K
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21.2 Ionic liquids 1477 According t
Page 1503 and 1504:
21.2 Ionic liquids 1479 Acidic melt
Page 1505 and 1506:
21.2 Ionic liquids 1481 21 C.L. Hus
Page 1507 and 1508:
21.2 Ionic liquids 1483 110 G.P. Li
Page 1509 and 1510:
21.3 Oxide solubilities in ionic me
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Page 1513 and 1514:
Page 1515 and 1516:
Page 1517 and 1518:
Page 1519 and 1520:
Page 1521 and 1522:
21.4 Alternative cleaning technolog
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Page 1525 and 1526:
Page 1527 and 1528:
Page 1529 and 1530:
Page 1531 and 1532:
1508 Klaus-Dirk Henning Application
Page 1533 and 1534:
1510 Klaus-Dirk Henning 22.1.2.2 Ad
Page 1535 and 1536:
1512 Klaus-Dirk Henning point the a
Page 1537 and 1538:
1514 Klaus-Dirk Henning Figure 22.1
Page 1539 and 1540:
Page 1541 and 1542:
1518 Klaus-Dirk Henning Table 22.1.
Page 1543 and 1544:
Page 1545 and 1546:
1522 Klaus-Dirk Henning Regeneratio
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1524 Klaus-Dirk Henning • activit
Page 1549 and 1550:
1526 Klaus-Dirk Henning adsorption
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Page 1557 and 1558:
1534 Klaus-Dirk Henning vent conden
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Page 1565 and 1566:
1542 Klaus-Dirk Henning 12 H. Krill
Page 1567 and 1568:
1544 Isao Kimura Table 22.2.1. Appl
Page 1569 and 1570:
1546 Isao Kimura Table 22.2.2. Typi
Page 1571 and 1572:
1548 Isao Kimura 22.2.4 SOLVENT REC
Page 1573 and 1574:
1550 Isao Kimura Figure 22.2.9. Flo
Page 1575 and 1576:
1552 Isao Kimura • Difficult in d
Page 1577 and 1578:
1554 Isao Kimura Figure 22.2.12. Fl
Page 1579 and 1580:
1556 Denis Kargol Figure 22.3.1. So
Page 1581 and 1582:
1558 Denis Kargol Figure 22.3.4. AS
Page 1583 and 1584:
1560 K. A. Magrini, et al. and Olli
Page 1585 and 1586:
1562 K. A. Magrini, et al. ysis of
Page 1587 and 1588:
1564 K. A. Magrini, et al. Figure 2
Page 1589 and 1590:
1566 K. A. Magrini, et al. On the l
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1568 K. A. Magrini, et al. ating te
Page 1593 and 1594:
1570 K. A. Magrini, et al. Cummings
Page 1595 and 1596:
1572 Hanadi S. Rifai, Charles J. Ne
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1618 Barry J. Spargo, James G. Muel
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1632 George Wypych number of 1 or e
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1634 George Wypych In addition to t
Page 1659 and 1660:
1636 George Wypych d diameter of gr
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1638 George Wypych wax-containing c
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1640 George Wypych product of inven
Page 1665 and 1666:
1642 George Wypych selection of sol
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1644 George Wypych fining processes
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1646 George Wypych requires several
Page 1671 and 1672:
1648 George Wypych crease color str
Page 1673 and 1674:
1650 George Wypych tion. The patent
Page 1675 and 1676:
1652 George Wypych 75 M Solinas, T
Page 1677 and 1678:
1658 Index anhydrous form 282 anili
Page 1679 and 1680:
1660 Index 1-chlorooctane 826 chlor
Page 1681 and 1682:
1662 Index term 750 dipole moment 1
Page 1683 and 1684:
1664 Index Friedel-Crafts alkylatio
Page 1685 and 1686:
1666 Index method 245 laser 689 lat
Page 1687 and 1688:
1668 Index O octane 127,185 1-octan
Page 1689 and 1690:
1670 Index Prandtl number 392 Praus
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1672 Index function 137 preferentia
Page 1693 and 1694:
1674 Index change 350 time scale 33
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