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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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390 Seung Su Kim, Jae Chun Hyun<br />

The Antoine equation coefficients A, B, C for various organic solvents can be found<br />

elsewhere. 19 The UNIFAC group contribution method was used to calculate the activity coefficient<br />

<strong>of</strong> each solvent. 49<br />

7.3.2.3 Heat and mass transfer coefficient<br />

The rate <strong>of</strong> heat transfer to the coating depends on the two factors as shown in Equation<br />

7.3.2: the difference between the temperature <strong>of</strong> coating and ambient air (the driving force)<br />

and the geometry where the heat transfer occurs (heat transfer coefficient). The heat transfer<br />

coefficient is a function <strong>of</strong> the nozzle geometry and blowing air properties. Many variables<br />

affect the heat transfer coefficient <strong>of</strong> nozzles, such as nozzle geometry and size, nozzle to<br />

coating surface distance, nozzle to nozzle spacing, velocity <strong>of</strong> air at the nozzle exit and air<br />

motion above the coating surface. 37,45<br />

Therefore the average heat transfer coefficient <strong>of</strong> a zone can be expressed as follows,<br />

where:<br />

( ) ( )<br />

h = f Geometry <strong>of</strong> nozzle,Pro perties <strong>of</strong> air × f w<br />

[7.3.5]<br />

h average heat transfer coefficient <strong>of</strong> a zone<br />

w velocity <strong>of</strong> air at the nozzle exit.<br />

Figure 7.3.3. Schematic diagram <strong>of</strong> modeled drying <strong>of</strong> coated film. [After reference 28].<br />

The accuracy <strong>of</strong> drying rate calculation greatly depends on the proper estimation <strong>of</strong> the<br />

heat and mass transfer coefficient <strong>of</strong> nozzles. Many researches have been done to find out<br />

the heat transfer coefficient <strong>of</strong> nozzles, among them the Martin’s correlation is the notable<br />

one which correlates the geometry <strong>of</strong> impinging jet nozzle and air velocity to the heat and<br />

mass transfer coefficients. 37 For a multiple slot jet nozzles, which is depicted in Figure<br />

7.3.4, Martin suggested following empirical correlation,

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