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Handbook of Solvents - George Wypych - ChemTech - Ventech!

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962 <strong>George</strong> <strong>Wypych</strong><br />

Table 14.18.2. Reported solvent transfers from the organic chemical industry in 1995<br />

[Data from Ref. 2]<br />

Solvent Amount, kg/year Solvent Amount, kg/year<br />

allyl alcohol 210,000 ethylbenzene 980,000<br />

benzene 420,000 ethylene glycol 6,800,000<br />

n-butyl alcohol 1,500,000 hexane 770,000<br />

sec-butyl alcohol 1,700,000 isopropyl alcohol 85,000<br />

tert-butyl alcohol 12,500,000 methanol 23,000,000<br />

carbon disulfide 96,000 methyl ethyl ketone 800,000<br />

carbon tetrachloride 12,000 methyl isobutyl ketone 390,000<br />

chlorobenzene 130,000 N-methyl-2-pyrrolidone 110,000<br />

chlor<strong>of</strong>orm 92,000 methyl tert-butyl ether 210,000<br />

cresol 430,000 pyridine 33,000<br />

m-cresol 720,000 tetrachloroethylene 138,000<br />

o-cresol 57,000 toluene 4,400,000<br />

p-cresol 870,000 1,2,4-trichlorobenzene 8,000<br />

cyclohexane 900,000 1,1,1-trichloroethane 290,000<br />

cyclohexanol 3,700 trichloroethylene 42,000<br />

dichloroethane 230,000 xylene 4,000,000<br />

1,2-dichloroethylene 1,000 m-xylene 51,000<br />

dichloromethane 870,000 o-xylene 460,000<br />

N,N-dimethylformamide 370,000 p-xylene 1,700<br />

14.18 ORGANIC CHEMICAL INDUSTRY<br />

<strong>George</strong> <strong>Wypych</strong><br />

ChemTec Laboratories, Inc., Toronto, Canada<br />

The chemical industry operates about 1000 plants in the USA with 53 companies producing<br />

50% <strong>of</strong> the total output <strong>of</strong> $65 billion in sales and employing 125,000 people. There are<br />

point source solvent emissions (e.g., laboratory hoods, distillation units, reactors, storage<br />

tanks, vents, etc.), fugitive emissions (e.g., pump valves, flanges, sample collectors, seals,<br />

relief devices, tanks), and secondary emissions (waste water treatment units, cooling<br />

towers, spills). Organic liquid wastes containing solvent are generated from processes such<br />

as equipment washing, surplus chemicals, product purification, product reaction,<br />

housekeeping, etc.

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