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LINEAR ALKYLBENZENE SULFONATE (LAS) - UNEP Chemicals

LINEAR ALKYLBENZENE SULFONATE (LAS) - UNEP Chemicals

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OECD SIDS <strong>LINEAR</strong> <strong>ALKYLBENZENE</strong> <strong>SULFONATE</strong> (<strong>LAS</strong>)<br />

Reliability: 4 Not assignable. This study was given a reliability score of 4 because all the<br />

original reports reviewed by the authors were not directly reviewed in the<br />

compilation of this robust summary.<br />

(e)<br />

Type of test: static [ ]; semi-static [X]; flow-through [ ]; open-system [ ]; closed-system [<br />

]<br />

Species: Daphnia magna (Crustacea)<br />

Endpoint: Mortality [X]; Reproduction rate [X]<br />

Exposure period: 21days<br />

Results: NOEC = 1.25-3.25 mg/L; LOEC = 2.25-3.75 mg/L<br />

Geometric Mean NOEC = 1.99 mg/L (mean of studies using 5 different<br />

diets)<br />

Analytical monitoring: Yes [ ] No [ ] ? [X]<br />

Method: ASTM proposed standard practice for conducting renewal life cycle toxicity<br />

tests with Daphnia magna. Draft No. 1, August 1982. Ten 250 m/L beakers<br />

were used for each test concentration. Seven beakers contained one daphnid<br />

each and three beakers contained five daphnids each, for a total of 22<br />

daphnids per concentration. All conditions were maintained as per protocol.<br />

GLP: Yes [ ] No [] ? [X]<br />

Test substance: Commercial C10-13 <strong>LAS</strong>, average chain length C11.8 (CAS #68411-30-3).<br />

Remarks: NOEC and LOEC values represent the range of results from five tests using<br />

different diets. Diet had at most a three-fold effect on the results, which is<br />

within the variation expected within the tests themselves. Therefore, results<br />

of different diets can be considered roughly equivalent to five replications of<br />

the same diet. This is a key study for chronic aquatic toxicity to invertebrates<br />

(see SIAR Table 12).<br />

Reference: Taylor, M.J. 1985. Effect of diet on the sensitivity of Daphnia magna to<br />

linear alkylbenzene sulfonate. In: Cardwell, R.D., Purdy, R. and Bahner,<br />

R.C. Aquatic Toxicology and Hazard Assessment. Seventh Symposium pp.<br />

53-72. ASTM STP 854, America Society for Testing and Materials,<br />

Philadelphia.<br />

Reliability: 2 Valid with restrictions<br />

(f)<br />

Type of test: static [ ]; semi-static [ X ]; flow-through [ ]; open-system [X]; closed-system<br />

[ ]<br />

Species: Daphnia magna (Crustacea)<br />

Endpoint: Mortality [ ]; Reproduction rate [X]; Other [ ]<br />

Exposure period: 21 day<br />

Results: NOEC = 0.3 mg/L<br />

Analytical monitoring: Yes [ ] No [X] ? [ ]<br />

Method: OECD Guide-line 202, part 2 “Daphnia sp., Reproduction Test<br />

GLP: Yes [ ] No [ ] ? [X]<br />

Test substance: C10-13 <strong>LAS</strong>, with average chain length of C11.8 (CAS #68411-30-3)<br />

Remarks: Information as cited in IUCLID Data Sheet for CAS #68411-30-3. Natural<br />

water 3x weekly renewal pH 6.0-8.5; 20 + /-2 ºC; life-stage: 6-24 h.<br />

Reference: European Commission. 2000a. Benzenesulfonic acid, C10-13-alkyl derivs.,<br />

sodium salts. Year 2000 CD-ROM edition, citing Henkel KGaA.<br />

Reliability: 4 Not assignable. The original study was not available for review.<br />

(g)<br />

Type of test: static [ ]; semi-static [X]; flow-through [ ]; other [ ]; open-system [ ];<br />

closed-system [ ]<br />

Species: Daphnia magna (Crustacea)<br />

Endpoint: Mortality [ ]; Reproduction rate [X]; Other [ ]<br />

<strong>UNEP</strong> PUBLICATIONS 211

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