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LINEAR ALKYLBENZENE SULFONATE (LAS) - UNEP Chemicals

LINEAR ALKYLBENZENE SULFONATE (LAS) - UNEP Chemicals

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OECD SIDS <strong>LINEAR</strong> <strong>ALKYLBENZENE</strong> <strong>SULFONATE</strong> (<strong>LAS</strong>)<br />

i: Default assumption<br />

j: Surface area of the palm of one hand (EPA Exposure Factors Handbook)<br />

Exposure to laundry and fabric conditioning product residual on clothing<br />

[A x PR x PT x DA x CF] x PF<br />

BW<br />

Liquid<br />

Laundry<br />

Detergent<br />

Dry Laundry<br />

Detergent<br />

Tablet<br />

Laundry<br />

Detergent<br />

Fabric<br />

conditioner<br />

(dryersheet)<br />

Amount Per Use (A) (g/day or g/wash) 121 a 121 a 135 a 3 a<br />

Percent Retained on Clothing (PR) (%) 1% a 1% a 1% a 10% a<br />

Percent Transferred from Clothing to Skin<br />

(PT) (%)<br />

1% a 1% a 1% a 1% a<br />

Dermal Absorption (DA) (%) 100% b 100% b 100% b 100% b<br />

Conversion Factor (CF) (1000 mg/g) 1000 1000 1000 1000<br />

Female body weight (BW) (kg) 60 c 60 c 60 c 60 c<br />

<strong>LAS</strong> concentration in product formulation<br />

(PF) g (%)<br />

1-25% d 5-25% d 5-25% d 0.1 – 0.5% d<br />

References:<br />

a: SDA Habit and Practice Survey<br />

b: Default assumption<br />

c: EU Technical Guidance Document, 1996<br />

d: <strong>LAS</strong> Coalition Survey, Min-Max values<br />

Exposure to face and hand soap residual after use<br />

[FQ x A x PR x DA x CF] x PF<br />

BW<br />

Bar Soap<br />

Bar Soap<br />

Hand<br />

Face<br />

Frequency of Use (FQ) (use/day) 6 a 1 a<br />

Amount Per Use (A) (g/use) 0.36 a 0.27 a<br />

Percent Retained on Skin (PR) (%) 1% e 1% e<br />

Dermal Absorption (DA) (%) 100% b 100% b<br />

Conversion Factor (CF) (1000 mg/g) 1000 1000<br />

Female body weight (BW) (kg) 60 c 60 c<br />

<strong>LAS</strong> concentration in product formulation (PF) g (%) 1-5% d 1-5% d<br />

References:<br />

a: SDA Habit and Practice Survey<br />

b: Default assumption<br />

c: EU Technical Guidance Document, 1996<br />

d: <strong>LAS</strong> Coalition Survey, Min-Max values<br />

e: CTFA 2003 data<br />

(3) Model Outputs<br />

Exposure during the activity/use of diluted and undiluted laundry and dishwashing products and<br />

diluted and undiluted hard surface cleaning products<br />

Potential Dermal Exposure<br />

(mg/kg/day) a<br />

Laundry Pre-Treatment (diluted) 3.0E-3 to 6.0E-3<br />

Neat Laundry Pre-Treatment (undiluted) 5.0E-3 to 1.0E-2<br />

Hand-wash of Laundry (diluted) 4.7E-5 to 1.2E-3<br />

<strong>UNEP</strong> PUBLICATIONS 88

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