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LINEAR ALKYLBENZENE SULFONATE (LAS) - UNEP Chemicals

LINEAR ALKYLBENZENE SULFONATE (LAS) - UNEP Chemicals

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OECD SIDS <strong>LINEAR</strong> <strong>ALKYLBENZENE</strong> <strong>SULFONATE</strong> (<strong>LAS</strong>)<br />

Species Endpoint EC10 EC50<br />

Chenopodium album Growth 164<br />

Amaranthus retroflexus Growth 142<br />

Nigella arvensis Growth 132<br />

Galinsoga parviflora Growth 90<br />

Sorghum bicolour Growth 137<br />

Helianthus annuus Growth 289<br />

Phaseolus aureus Growth 316<br />

Avena sativa Growth 50 300<br />

Sinapis alba Growth 200 300<br />

Test Substance: <strong>LAS</strong> (unspecified)<br />

Remarks: Values are extracted from a variety of original references and compiled for<br />

this article. NOEC values were extrapolated by applying an assessment<br />

factor of 10 to the EC50. This is considered an unreliable assumption as<br />

measured acute-to-chronic ratios for <strong>LAS</strong> in plants vary between 2 and 6.<br />

Reference: Jensen, J., Lokke, H., Holmstrup, M., Krogh, P.H. and Elsgaard, L. 2001.<br />

Effects and risk assessment of linear alkylbenzene sulfonates in agricultural<br />

soil. 5. Probabilistic risk assessment of linear alkylbenzene sulfonates in<br />

sludge-amended soils. Environmental Toxicology and Chemistry 20:1690-<br />

1697.<br />

Reliability: 4 This study was given a reliability score of 4 because the original reports<br />

reviewed by the authors were not directly reviewed in the compilation of this<br />

robust summary.<br />

(b)<br />

Species: Grass, beans, radishes, potatoes<br />

Radiolabel: Yes<br />

Results: No adverse effects on plant biomass were observed at the concentrations<br />

tested [initial concentrations in soil = 27.2 mg/kg (grass, beans, radishes); =<br />

16.2 mg/kg (potatoes)]<br />

Temperature: Room temperature<br />

Method: Soil cores taken from two ecosystems were collected and placed in a climate<br />

controlled “plant metabolism box”. Ecosystem Section I consisted of a<br />

heavy, clay-like soil. Radiolabeled <strong>LAS</strong> (a defined mixture) absorbed to<br />

digested sludge was incorporated into the soils, after which the soils were<br />

planted with either grass, bush beans and radishes (Section I) or potatoes<br />

(Section II). The test systems were maintained under a defined standard<br />

climate (i.e., an average day in June in Northern Germany) for the vegetative<br />

period (76 and 106 days, respectively for Sections I and II). At the end of<br />

the growing season samples were collected from plants and soil and<br />

subjected to radioanalysis.<br />

GLP: Yes [ ] No [ ] ? [X]<br />

Test Substance: <strong>LAS</strong>. The authors state that they tested a defined mixture of <strong>LAS</strong>, but do not<br />

report the composition in this paper.<br />

Reference: Figge, K. and Schoberl, P. 1989. <strong>LAS</strong> and the application of sewage sludge<br />

in agriculture. Tenside Surf. Det. 26:122-128.<br />

Reliability: 2 Valid with restrictions<br />

(c)<br />

Species: radish, tomato, oats<br />

Endpoint: Emergence [ ]; Growth [X]; Other [ ]<br />

Exposure period: 14 day<br />

Results: EC50 >77.1 mg/kg soil dw<br />

NOEC = 25.7 mg/kg soil dw<br />

Method: OECD Guide-line 208 “Terrestrial Plants, Growth Test”.<br />

<strong>UNEP</strong> PUBLICATIONS 230

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