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Sempere Alemany, Francisco Javier.pdf - RUA - Universidad de ...

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430 Apéndice D<br />

D.1 – Desarrollo <strong>de</strong>l mo<strong>de</strong>lo cinético aplicado a la <strong>de</strong>scomposición térmica<br />

(TGA) <strong>de</strong>l EVA.<br />

(D1,EVA))<br />

(D2,EVA)<br />

(D,EVA(i))<br />

(D.1.1)<br />

(D.1.2)<br />

(D.1.3)<br />

(D.1.4)<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎝<br />

⎛<br />

−<br />

⋅<br />

−<br />

⋅<br />

⋅<br />

−<br />

=<br />

r<br />

a<br />

n<br />

EVA<br />

r<br />

EVA<br />

T<br />

T<br />

R<br />

E<br />

w<br />

k<br />

dt<br />

dw EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

1<br />

1<br />

exp<br />

,<br />

1<br />

,<br />

1<br />

,<br />

1<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

−<br />

⋅<br />

−<br />

⋅<br />

⋅<br />

−<br />

−<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

−<br />

⋅<br />

−<br />

⋅<br />

⋅<br />

⋅<br />

=<br />

=<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

+<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

=<br />

r<br />

a<br />

n<br />

EVA<br />

r<br />

r<br />

a<br />

n<br />

EVA<br />

r<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

EVA<br />

D<br />

EVA<br />

EVA<br />

T<br />

T<br />

R<br />

E<br />

w<br />

k<br />

T<br />

T<br />

R<br />

E<br />

w<br />

k<br />

s<br />

dt<br />

dw<br />

dt<br />

dw<br />

dt<br />

dw<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

1<br />

1<br />

exp<br />

1<br />

1<br />

exp<br />

,<br />

2<br />

,<br />

2<br />

*<br />

,<br />

2<br />

,<br />

1<br />

,<br />

1<br />

,<br />

1<br />

*<br />

*<br />

*<br />

,<br />

1<br />

,<br />

2<br />

,<br />

1<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

−<br />

⋅<br />

−<br />

⋅<br />

⋅<br />

−<br />

=<br />

r<br />

a<br />

n<br />

i<br />

EVA<br />

r<br />

i<br />

EVA<br />

T<br />

T<br />

R<br />

E<br />

w<br />

k<br />

dt<br />

dw i<br />

EVA<br />

D<br />

i<br />

EVA<br />

D<br />

i<br />

EVA<br />

D<br />

1<br />

1<br />

exp<br />

)<br />

(<br />

,<br />

)<br />

(<br />

,<br />

)<br />

(<br />

,<br />

)<br />

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)<br />

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)<br />

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)<br />

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)<br />

(<br />

)<br />

(<br />

,<br />

)<br />

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2<br />

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2<br />

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2<br />

*<br />

,<br />

1<br />

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1<br />

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1<br />

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1<br />

)<br />

1<br />

(<br />

)<br />

(<br />

)<br />

1<br />

(<br />

)<br />

1<br />

(<br />

i<br />

EVA<br />

D<br />

i<br />

EVA<br />

D<br />

i<br />

EVA<br />

i<br />

EVA<br />

D<br />

i<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

G<br />

s<br />

S<br />

s<br />

k<br />

i<br />

EVA<br />

G<br />

s<br />

S<br />

s<br />

k<br />

EVA<br />

G<br />

s<br />

EVA<br />

s<br />

k<br />

EVA<br />

⋅<br />

−<br />

+<br />

⋅<br />

⎯<br />

⎯<br />

⎯ →<br />

⎯<br />

⋅<br />

−<br />

+<br />

⋅<br />

⎯<br />

⎯<br />

⎯ →<br />

⎯<br />

⋅<br />

−<br />

+<br />

⋅<br />

⎯<br />

⎯<br />

⎯ →<br />

⎯<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

⎟<br />

⎟<br />

⎠<br />

⎞<br />

⎜<br />

⎜<br />

⎝<br />

⎛<br />

−<br />

⋅<br />

−<br />

⋅<br />

⋅<br />

⋅<br />

=<br />

r<br />

a<br />

n<br />

EVA<br />

r<br />

EVA<br />

D<br />

EVA<br />

T<br />

T<br />

R<br />

E<br />

w<br />

k<br />

s<br />

dt<br />

dS EVA<br />

D<br />

EVA<br />

D<br />

EVA<br />

D<br />

1<br />

1<br />

exp<br />

,<br />

2<br />

,<br />

2<br />

*<br />

,<br />

2<br />

,<br />

2

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