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Plenarvorträge - DPG-Tagungen

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Halbleiterphysik Donnerstag<br />

HL 39 Hauptvortrag Kaiser<br />

Zeit: Donnerstag 14:30–15:15 Raum: H15<br />

Hauptvortrag HL 39.1 Do 14:30 H15<br />

The Dramatic Developments of Optical Lithography — •W.<br />

Kaiser — Carl Zeiss SMT AG, 73446 Oberkochen<br />

Lithography is the key technology in the chip manufacturing process<br />

to enable continuous shrinking of electronic components on modern ICs,<br />

resulting in cheaper, faster, and less power consumptive devices.<br />

Based on optical design concepts for photographic and microscopy<br />

lenses the optical lithography has experienced a fulminant development<br />

HL 40 SiC I<br />

seen through the last three decades.<br />

The most advanced systems today work at a wavelength of 193nm<br />

and are able to achieve resolution of 90nm and below in high volume<br />

production.<br />

In this presentation the actual state of the art for these systems and<br />

the optical technologies will be shown.<br />

Also recent developments like Immersion Lithography, the trend to<br />

shorter wavelength (157nm) and the long-term perspective to EUV-<br />

Lithography will be addressed.<br />

Zeit: Donnerstag 15:15–16:30 Raum: H15<br />

HL 40.1 Do 15:15 H15<br />

Homoepitaxial growth of 4H-SiC:Ge alloys on 4H-SiC (0001)<br />

substrates by Molecular Beam Epitaxy — •Petia Weih 1 ,<br />

Thomas Stauden 1 , Lothar Spieß 2 , Henry Romanus 2 , Oliver<br />

Ambacher 1 , and Jörg Pezoldt 1 — 1 FG Nanotechnologie, Zentrum<br />

für Mikro- und Nanotechnologien, TU Ilmenau, PF100565, D-98693<br />

Ilmenau, Germany — 2 FG Werkstofftechnologie, Zentrum für Mikround<br />

Nanotechnologien, TU Ilmenau, PF100565, D-98693 Ilmenau,<br />

Germany<br />

Up to date the only intrinsic heterostructures based on SiC are beta-<br />

SiC/alpha-SiC heterojunctions using different bandgaps of different polytypes,<br />

which could not be improved into commercial applications because<br />

of unsolved technological problems. The epitaxy of SiC:Ge alloys provides<br />

the opportunity of bandgap engineering and the realization of alternative<br />

SiC based heterostructures. The draw backs of SiC:Ge alloys are<br />

the thermodynamic instability and the immiscibility of Ge in SiC, which<br />

must be overcome by nonequilibrium material synthesis methods such<br />

as ion beam synthesis or molecular beam epitaxy. In this work for the<br />

first time SiC:Ge thin films were grown homoepitaxially by solid source<br />

molecular beam epitaxy applying (a) continuous fluxes of Si-, C- and Geflux<br />

or (b) atomic layer epitaxy (subsequent deposition of C and Si/Ge)<br />

on on-axis 4H-SiC (0001) substrates. The surface morphology, the chemical<br />

composition and the structure of the grown layers were analysed by<br />

atom force microscopy, scanning electron microscopy with accompanying<br />

energy dispersive X-ray analysis, secondary ion mass spectroscopy and<br />

transmission electron microscopy, respectively.<br />

HL 40.2 Do 15:30 H15<br />

Micro-electromechanical systems based on 3C-SiC/Si heterostructures<br />

— •Christian Förster, Volker Cimalla,<br />

Michael Fischer, Klemens Brückner, Matthias Hein, Jörg<br />

Pezoldt, and Oliver Ambacher — FG Nanotechnologie und FG<br />

Hochfrequenztechnik, Zentrum für Mikro- und Nanotechnologien, TU<br />

Ilmenau, PF100565, 98693 Ilmenau<br />

Wide bandgap semiconductors like SiC are excellent materials for high<br />

temperature, high frequency and high power applications. Furthermore<br />

the properties of SiC are typical for materials suitable for modern applications<br />

in micro-sensors, micro-actuators as well as in micro- and nanoelectromechanical<br />

systems (MEMS, NEMS). Novel applications of SiC/Si<br />

based MEMS and NEMS are dosing and sensor systems for micro- and<br />

nano-fluidic systems, e.g. for fast and reliable biomedical testing and<br />

analysis. We have developed a technology for processing SiC/Si-based<br />

MEMS and NEMS. A micro dosing head for pulmonary amount of liquid<br />

in very small area are realized. This dosing head consist of parallel<br />

operating multi micro pipes running at a defined pressure. Furthermore,<br />

we used 3C-SiC/Si heterostructures to process resonator bars having geometries<br />

in the sub micro meter range. These bars open the possibility<br />

to evaluate the viscosity of water based nano-droplets or to measure the<br />

mass of particles, for example proteins, positioned on the bars.<br />

HL 40.3 Do 15:45 H15<br />

Deep Levels of Gadolinium in Silicon Carbide — •Gunnar<br />

Pasold 1 , Fanny Albrecht 1 , Christian Hülsen 1 , Rainer Sielemann<br />

2 , Wolf Dietrich Zeitz 2 , and Wolfgang Witthuhn 1 —<br />

1 Friedrich-Schiller-Universität Jena, Institut für Festkörperphysik, Max-<br />

Wien-Platz 1, 07743 Jena — 2 Hahn- Meitner- Institut Berlin, Glienicker<br />

Straße 100, D-14109 Berlin<br />

Epitaxial layers of hexagonal silicon carbide (SiC) were doped with<br />

the radioactive isotope 149 Gd by recoil-implantation at the HMI (Berlin).<br />

Deep Level Transient Spectra (DLTS) were taken, repeatedly, during the<br />

elemental transmutation 149 Gd → 149 Eu (T1 /2 =9.5 d)<br />

Spectra taken on p-type SiC reveal two deep levels<br />

(ET=EV+0.94±2 eV and ET=EV+0.45±1 eV), undergoing a decrease<br />

in concentration with a half-life of 11±1 d identifying them as Gd<br />

correlated. Whereas the deeper one has been found in 4H and 6H-SiC,<br />

the lower one is observable in the 4H polytype only.<br />

Deep levels with increasing concentrations indicating levels caused by<br />

the daughter element Eu were not observed in the part of the band-gap<br />

of SiC investigated. N-type SiC samples implanted with 149 Gd show no<br />

time dependent deep level concentrations.<br />

HL 40.4 Do 16:00 H15<br />

Oxynitrides on 4H-SiC(0001) — •Patrick Hoffmann and Dieter<br />

Schmeißer — BTU Cottbus, Lehrstuhl Angewandte Physik II /<br />

Sensorik, Universitätsplatz 3-4, 03044 Cottbus<br />

It will be reported on the growth of oxynitride thin layers (≤10nm) on<br />

(0001)-oriented 4H-SiC surfaces. The oxynitride layers were grown by a<br />

thermal treatment of the samples in low pressure N2O ambient. By varying<br />

the growth conditions (N2O pressure, sample temperature, growth<br />

time) different layers were made.<br />

The grown layers were investigated by photoelectron spectroscopy<br />

(XPS) for chemical analysis and by AFM/STM for analysis of the surface<br />

morphology. Concerning the chemical analysis it will be discussed<br />

the general nitrogen content of the samples, the composition of the films<br />

(e.g. content of silicon nitride Si3N4 and silicon oxynitride SiOxNy) and<br />

the sub-oxides which build the interface between SiC and the oxynitride<br />

layers. Concerning the surface morphology mainly the roughness will be<br />

discussed.<br />

The so obtained results for oxynitride thin films on 4H-SiC will be<br />

compared to similarly prepared oxynitride layers on Si(111) investigated<br />

in the past.<br />

HL 40.5 Do 16:15 H15<br />

The sequential annealing of radiation-induced intrinsic defects<br />

in SiC — •M.V.B. Pinheiro, U. Gerstermann, E. Rauls, Th.<br />

Frauenheim, S. Greulich-Weber, and J.-M. Spaeth — Departament<br />

Physik, Universit”at Paderborn, Warburger Str. 100, 33098, Paderborn<br />

, Deutschland<br />

The understanding of sequential annealing dynamics of radiationinduced<br />

defects in SiC has been of highly technological interest. The<br />

main reason for this is that most SiC devices require ion-implantation<br />

doping, which generates intrinsic defects with a high thermal stability.<br />

In this work we present a complete model for the sequential annealing<br />

of several defects generated by electron-irradiation in SiC. Among these<br />

defects there are several unidentified ones that disappear above 150C, the<br />

isolated silicon vacancy that between 600C and 750C is converted in the<br />

silicon antisite - carbon vacancy pair, and finally the D1 center whose concentration<br />

strongly increases above 900C. The latter is the end-product<br />

visible with photoluminescence up to 1700C. Our model is based on a<br />

systematic isochronal annealing investigation performed in 6H-SiC and<br />

4H-SiC with photoluminescence (PL), electron-paramagnetic resonance<br />

(EPR) and magnetic circular dichroism of the absorption (MCDA), and<br />

is fully consistent with ab-initio calculations.

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