Angelika Semmler - KOPS - Universität Konstanz

10 Anhang
H-cyclo[Lys-His-Pro-Gln-His-Gly-Glu]-βAla-Pro-Pro-Arg-NH2 (92)
Analytische RP-HPLC: (8-30% B in 45 min) tR = 13,1 min
ESI-QTOF: 1234,6576 m/z (±1,9 ppm)
Berechnet: C54H84N21O13 + (1234,6552 m/z)
mAU
214nm,4nm (1.00)
800
700
600
500
400
300
200
100
0
-100
-200
0
0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 min
Intens.
x105
2.5
2.0
1.5
1.0
0.5
0.0
Intens.
x105
2.5
2.0
1.5
1.0
0.5
0.0
180
1021.3025
1234.6576
13.123
%
B.Conc.(Method)
90
80
70
60
50
40
30
20
10
+MS, 1.7min #100
1000 1500 2000 2500 3000 3500 4000 4500 5000m/z
1234.6576
1256.6400
1292.6183
1314.5974
+MS, 1.7min #100
1200 1220 1240 1260 1280 1300 1320 m/z