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International Review of Waste Management Policy - Department of ...

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1020<br />

3. Bioaerosols<br />

Of these, the first two impacts differ depending on the nature <strong>of</strong> the composting<br />

process. This is discussed in Sections 63.8.3.1 and 63.8.3.2. Bioaerosols are<br />

discussed in Section 63.8.3.3.<br />

63.8.3.1 Air Quality Impacts in Windrow Composting<br />

As was previously indicated in Section 63.8.1, our analysis assumes that 10% <strong>of</strong> the<br />

total nitrogen content <strong>of</strong> the waste is released in some form and that <strong>of</strong> this 10%,<br />

88% is released as NH3 in windrow systems that operate without the use <strong>of</strong> a bi<strong>of</strong>ilter.<br />

This results in NH3 emissions <strong>of</strong> 795 g <strong>of</strong> NH3 per tonne <strong>of</strong> waste to the facility.<br />

Although relatively few studies have investigated emissions <strong>of</strong> VOCs from composting<br />

processes, the UK’s Environment Agency did measure emissions from sites. These<br />

are shown in Table 63-25.<br />

Table 63-25: Emissions <strong>of</strong> VOCs from Monitoring <strong>of</strong> Compost Facilities<br />

Compounds Compounds Detected Detected<br />

g / / tonne tonne <strong>of</strong> <strong>of</strong> MSW<br />

MSW<br />

m,p Xylene [108-38-3; 106-42-3] 0.81<br />

Nonane [111-84-2] 0.44<br />

o Xylene [95-47-6] 0.54<br />

Beta.-Pinene [127-91-3] 3.7<br />

Ocimene [13877-91-3] 3.0<br />

D-Limonene [5989-27-5] 10.5<br />

Undecane [1120-21-4] 2.4<br />

Dodecane [112-40-3] 1.2<br />

Methyl-(methylethyl)-Cyclohexane [99-82-1] 1.5<br />

Total 24.0<br />

Source: Environment Agency (2000) Life Cycle Inventory Development for <strong>Waste</strong> <strong>Management</strong><br />

Operations: Composting and Anaerobic Digestion, R&D Project Record P1/392/4<br />

We have used the total Environment Agency figure – <strong>of</strong> 24 g <strong>of</strong> emission per tonne <strong>of</strong><br />

waste to the facility - with regard to the emission <strong>of</strong> VOCs from windrow composting<br />

processes.<br />

63.8.3.2 Air Quality Impacts In Vessel Composting Systems<br />

In in-vessel composting systems, NH3 is usually treated in bi<strong>of</strong>ilters. In bi<strong>of</strong>ilters, the<br />

nitrogen in the ammonia is converted to, in varying proportions, N2, NO and N2O.<br />

One study looking at MBT processes suggests a mass balance for a bi<strong>of</strong>ilter as shown<br />

in Figure 63-1. The figure suggests that, as regards N, for every 500 g <strong>of</strong> N entering<br />

the bi<strong>of</strong>ilter as NH3, an additional 111 g <strong>of</strong> N is emitted as N2O. This would imply a<br />

conversion ratio <strong>of</strong> 22%. On the other hand, the above figure suggests a low overall<br />

rate <strong>of</strong> destruction <strong>of</strong> NH3.<br />

29/09/09

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