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INTERDISCIPLINARY JOURNAL OF CONTEMPORARY RESEARCH IN BUSINESS<br />

14.1.1 DEGUMMING<br />

Before further process<strong>in</strong>g <strong>of</strong> the extracted crude oil, the crude oil has to be degummed.<br />

Degumm<strong>in</strong>g removes the phosphatides and mucilag<strong>in</strong>ous gums, which becomes <strong>in</strong>soluble<br />

<strong>in</strong> the oil when hydrated. Degumm<strong>in</strong>g is done for two primary reasons.<br />

i. To produce lecith<strong>in</strong> <strong>in</strong> the case <strong>of</strong> soybean and<br />

ii. To produce an oil suitable for long term storage or transport (the presence <strong>of</strong><br />

substantial amount <strong>of</strong> phosphatides lead to dark coloured and <strong>of</strong>f-flavoured oil).<br />

Phospholipids has both hydrophilic and lipophilic components that makes them excellent<br />

emulsifiers but they also allow faster spoilage <strong>of</strong> the oil because they are more<br />

susceptible to oxidation than triglycerides. Lecith<strong>in</strong> is an important by- product <strong>of</strong> the<br />

degumm<strong>in</strong>g process.<br />

Degumm<strong>in</strong>g is carried out us<strong>in</strong>g two methods.<br />

i. Degumm<strong>in</strong>g with water<br />

ii. Degumm<strong>in</strong>g with acid water.<br />

Degumm<strong>in</strong>g with water <strong>in</strong>volves mix<strong>in</strong>g the oil with about 2% water at 60-80 o C for about<br />

30 m<strong>in</strong>utes to hydrate the phosphatides, thereby reduc<strong>in</strong>g their solubility <strong>in</strong> the oil.<br />

Degumm<strong>in</strong>g with acid and water follows a similar procedure, except the oil is first<br />

vigorously mixed with about 0.1-0.5% <strong>of</strong> 50% solution <strong>of</strong> citric acid, malic acid or<br />

phosphoric acid and then mixed gently with 2% water. Degumm<strong>in</strong>g with acid and water<br />

also removes the non-hydratable phosphatides. Follow<strong>in</strong>g contact <strong>of</strong> the oil with water or<br />

acid and water, the oil is centrifuged to remove the precipitated materials.<br />

14.1.2 BLEACHING.<br />

With few exceptions such as olive oil, consumer expect their oil to have little or no<br />

colour. In addition, many pigments are pro-oxidants that will make the oil more<br />

susceptible to oxidation.<br />

Alkali ref<strong>in</strong>ed oil must be bleached to remove pigments, metallic components, residual<br />

soaps and traces <strong>of</strong> oxidation products. The exact process varies depend<strong>in</strong>g on the<br />

equipments used <strong>in</strong> the bleach<strong>in</strong>g process.<br />

The process generally <strong>in</strong>volves mix<strong>in</strong>g the oil with bleach<strong>in</strong>g earth (an acid treated<br />

bentonite clay) at about 100 o C under vacuum for about 5-30m<strong>in</strong>utes.The amount <strong>of</strong> the<br />

activated bleach<strong>in</strong>g earth used variesfrom1-3% depend<strong>in</strong>g on the level <strong>of</strong> the residual<br />

phosphatides present <strong>in</strong> the oil. The bleach<strong>in</strong>g earth is a natural clay <strong>of</strong> alum<strong>in</strong>ium silicate<br />

conta<strong>in</strong><strong>in</strong>g magnesium, calcium, sodium and iron; with PH 8, and apparent density <strong>of</strong> 0.7-<br />

0.9gml. The clay, absorbed components and precipitated materials are removed by<br />

filtration. Bleach<strong>in</strong>g <strong>of</strong> the oil can be achieved <strong>in</strong> the follow<strong>in</strong>g ways:<br />

i. By adsorption on solids<br />

ii. By leach<strong>in</strong>g<br />

iii. By catalytic hydrogenation<br />

iv. By chemical bleach<strong>in</strong>g agent.<br />

COPY RIGHT © 2011 Institute <strong>of</strong> <strong>Interdiscipl<strong>in</strong>ary</strong> Bus<strong>in</strong>ess <strong>Research</strong> 75<br />

JANUARY 2011<br />

VOL 2, NO 9

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