o-TOLUIDINE CAS N°: 95-53-4 - UNEP Chemicals

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OECD SIDS o-TOLUIDINE 1. GENERAL INFORMATION ID: 95-53-4 DATE: 07.01.2005 1.8.6 LISTINGS E.G. CHEMICAL INVENTORIES 1.9.1 DEGRADATION/TRANSFORMATION PRODUCTS 1.9.2 COMPONENTS 1.10 SOURCE OF EXPOSURE 1.11 ADDITIONAL REMARKS 1.12 LAST LITERATURE SEARCH 60 Type of search : Internal and External Chapters covered : 1 Date of search : 26.08.2003 18.03.2004 Type of search : Internal and External Chapters covered : 2 Date of search : 26.08.2003 18.03.2004 Type of search : Internal and External Chapters covered : 3, 4 Date of search : 26.08.2003 18.03.2004 Type of search : Internal and External Chapters covered : 5 Date of search : 02.01.2004 18.03.2004 1.13 REVIEWS Memo : CICAD Remark : CICAD is produced within the framework of the Inter-Organization Programme for the Sound Management of Chemicals, which is a cooperative programme of UNEP (United Nations Environment Programme), ILO (International Labour Organisation), and WHO (World Health Organization) (see www.who.int/entity/ipcs/ publications/cicad/en/cicad07.pdf.). Flag : Critical study for SIDS endpoint 07.01.2005 (14) UNEP PUBLICATIONS
OECD SIDS o-TOLUIDINE 2. PHYSICO-CHEMICAL DATA ID: 95-53-4 DATE: 07.01.2005 2.1 MELTING POINT Value : -24.4 - -16.3 °C Sublimation : Method : Year : 1999 GLP : Test substance : other TS: o-Toluidine, purity not specified Remark : A value of -24.4 °C for the alpha-form and a value of -16.3 °C for the betaform are given. Reliability : (2) valid with restrictions Data from handbook or collection of data Flag : Critical study for SIDS endpoint 08.06.2004 (8) Value : -16.3 °C Sublimation : Method : Year : 1995 GLP : Test substance : other TS: o-Toluidine, purity not specified Reliability : (2) valid with restrictions Data from handbook or collection of data 08.06.2004 (15) Value : -27.7 - -16.1 °C Sublimation : Method : Year : 2003 GLP : Test substance : other TS: o-Toluidine, purity not specified Remark : Pressure is given in at (technical atmosphere, 1 at = 1.033 atm) Result : Beilstein reports several melting point values from several different sources: Melting point (°C) =>crystallisation form not specified -27.7 -24.3 -23.7 =>alpha-form -24.4 -23.68 -21 -24.5 at 980.7 hPa =>beta-form -16.4 -16.25 -15.5 -16.1 at 980.7 hPa The atmospheric pressure was only detailed for two of the values. It is assumed that the other values were measured at standard atmospheric UNEP PUBLICATIONS 61
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o-TOLUIDINE CAS N°: 95-53-4 - UNEP Chemicals

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