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o-TOLUIDINE CAS N°: 95-53-4 - UNEP Chemicals

o-TOLUIDINE CAS N°: 95-53-4 - UNEP Chemicals

o-TOLUIDINE CAS N°: 95-53-4 - UNEP Chemicals

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OECD SIDS o-<strong>TOLUIDINE</strong><br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: <strong>95</strong>-<strong>53</strong>-4<br />

DATE: 07.01.2005<br />

98<br />

Reliability : (3) invalid<br />

Documentation insufficient for assessment<br />

15.06.2004 (82)<br />

Type :<br />

Inoculum : other: Chernozem soil<br />

Contact time :<br />

Degradation : 100 (±) % after 3 day(s)<br />

Result :<br />

Result : Degradation in soil:<br />

- 500 mg/kg Chernozem soil.<br />

- degradation took 3 days leaving a very stable product that persists > 3<br />

months.<br />

Reliability : (4) not assignable<br />

Original reference in Polish, not translated<br />

10.02.2004 (83)<br />

Type : aerobic<br />

Inoculum : other: river water microorganisms of a polluted river<br />

Concentration : 20 mg/l related to<br />

related to<br />

Contact time :<br />

Degradation : > 90 (±) % after 15 day(s)<br />

Result :<br />

Deg. product :<br />

Method : other: modified river die-away test (TOC-HANDAI)<br />

Year : 1997<br />

GLP : no data<br />

Test substance : other TS: o-Toluidine, purity is not specified<br />

Method : A river die-away test was developed by using an inoculum from river water<br />

at different sampling sites.<br />

River water samples were collected from an unpolluted (Takayama of the<br />

Minoh river) and a polluted site (Kitahshi of the Neya river) in Osaka, Japan<br />

and used as microorganism source. A filter method was used for the<br />

preparation of inoculum.<br />

o-Toluidine was added to 60 ml test tubes as sole carbon source at a<br />

concentration of 20 mg/l. 25 ml of the inoculum (artificial river water +<br />

microorganism source + chemical) were incubated at 25 °C with shaking in<br />

the dark for 14 days. A blank containing microorganisms without test<br />

chemical and a control carrying only the test chemical were included. TOC<br />

was measured periodically.<br />

Result : Microorganisms trapped from Takayama (unpolluted) were able to degrade<br />

less than 20 %. Microorganisms trapped from Kitahashi (polluted) started<br />

degrading o-toluidine from the 2nd day and reached a maximum by the 8th<br />

day. After 15 days more than 90 % of o-toluidine was degraded (result<br />

taken from a graph).<br />

Reliability : (2) valid with restrictions<br />

Test prodedure in accordance with national standard methods with<br />

acceptable restrictions<br />

18.06.2004 (84)<br />

Type : aerobic<br />

Inoculum : other: spiked river water of the river Elbe<br />

Contact time :<br />

Degradation : 50 (±) % after .8 hour(s)<br />

Result :<br />

Deg. product :<br />

Method : other: see method<br />

Year : 2002<br />

<strong>UNEP</strong> PUBLICATIONS

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