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m-Cresol - ipcs inchem

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OECD SIDS<br />

p-CRESOL<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 106-44-5<br />

DATE: 24.05.2004<br />

for low OC soils could be attributed to H-bond interactions between<br />

phenolic hydroxyl and clay surfaces (clay-content in these soils: 68% and<br />

86%).<br />

This type of adsorption can't be applied to explain the adsorption<br />

phenomenon (correlation between OC-content and adsorption), which<br />

usually occures in standard soils.<br />

Result : Koc = 3420 (Apison), 3350 (Fullerton), 115 (Dormont)<br />

Test condition : 3 soils tested: Dormont (pH 4.2; OC 1.2%), Apison (pH 4.5;<br />

OC 0.11%), Fullerton (pH 4.4; OC 0.05%)<br />

soil/water ratio 1:1 - 1:66<br />

initial TS concentration 0.5 - 1.0 mg/l<br />

incubation period 24 h<br />

Reliability : (3) invalid<br />

No standard soil was used in the test. Soils Apison and Fullerton have a<br />

very low OC-content.Suggested OC-content in OECD 106:0.6-3.5%; in<br />

67/548/EEC C.18: >0.3%) ).<br />

10.05.2004 (36)<br />

Type : adsorption<br />

Media : water - soil<br />

Air : % (Fugacity Model Level I)<br />

Water : % (Fugacity Model Level I)<br />

Soil : % (Fugacity Model Level I)<br />

Biota : % (Fugacity Model Level II/III)<br />

Soil : % (Fugacity Model Level II/III)<br />

Method :<br />

Year :<br />

Remark : the authors cite a log Koc of 2,70 (koc 501), but no details on the<br />

experiments are described nor the primary citation is given<br />

Reliability : (4) not assignable<br />

secondary literature, experimental details missing<br />

15.01.2003 (37)<br />

Type : adsorption<br />

Media : water - soil<br />

Air : % (Fugacity Model Level I)<br />

Water : % (Fugacity Model Level I)<br />

Soil : % (Fugacity Model Level I)<br />

Biota : % (Fugacity Model Level II/III)<br />

Soil : % (Fugacity Model Level II/III)<br />

Method :<br />

Year :<br />

Result : Neither Freundlich adsorption coefficients nor Koc values are reported in<br />

the article. The authors report the isotherms in graphic formate.<br />

In the Chemfate database citation of this article Freundlich adsorption<br />

coefficients (K) are estimated from the isotherms at about 50 ppm: 0.50<br />

E02 to 0.5 E01.<br />

The corresponding Koc values can be calculated as 560 to 10000.<br />

No explanation for the wide variety of the adsorpion coefficients is given.<br />

Test condition : 5 soils were tested: Davidson (pH 6.4; OC 0.3%), Molokai (pH 6.2; 0.5%),<br />

Fanno (pH 7.0; OC 0.9%), Mohave (pH 7.8; OC 0.4%), Ava (pH 4.5; OC<br />

0.4%)<br />

200 ml deionized water were added to 10 g of soil<br />

initial TS concentration 5 - 100 ppm<br />

temperatur 22 °C<br />

equilibration time 5 days<br />

Reliability : (3) invalid<br />

UNEP PUBLICATIONS 203

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