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m-Cresol - ipcs inchem

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OECD SIDS<br />

m- / p-CRESOL MIXTURE<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 15831-10-4<br />

DATE: 24.05.2004<br />

3.1.1 PHOTODEGRADATION<br />

308<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

Method : other (measured)<br />

Year : 1995<br />

GLP : no data<br />

Test substance : other TS: m-cresol, purity > 99 %<br />

Method : Determination of the temperature-dependency of the<br />

OH-radical reaction under simulated tropospheric conditions<br />

Remark : With a OH radical concentration of 1 000 000 molec cm-3 and<br />

a temperature of 299 K, the half-life is 3.8 h<br />

Result : kOH = 5.17 x 10E-12 exp[(686+-231)/T] cm3 molec.-1 s-1 for a<br />

temperature range of 299-373 K<br />

Test condition : test substance concentration 0.05-5 ppm<br />

reference compound (o-cresol) 0.05-2.3 ppm<br />

radical source methylnitrite 1.5-11 ppm together with NOx<br />

2-70 ppm<br />

Reliability : (1) valid without restriction<br />

Test procedure in accordance with generally accepted scientific standards;<br />

detailed documentation of test procedure and test conditions<br />

Flag : Critical study for SIDS endpoint<br />

12.05.2004 (8)<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

Method : other (measured): critical review<br />

Year : 1994<br />

GLP : no data<br />

Test substance : other TS: m-cresol, no purity reported<br />

Remark : With a OH radical concentration of 1 000 000 molec/cm3, the<br />

half-life is 3.0 h at room temperature<br />

Result : K[OH] = 64 [10E-12 cm3 molecule-1 s-1]<br />

K[NO3] = 9.74[10E-12 cm3 molecule-1 s-1]<br />

K[O3] = 1.9 [10E-19 cm3 molecule-1 s-1]<br />

Reliability : (1) valid without restriction<br />

Critical review, evaluation of all available experimental<br />

data<br />

Flag : Critical study for SIDS endpoint<br />

11.05.2004 (9)<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

Method : other (measured)<br />

Year : 1990<br />

GLP : no data<br />

Test substance : other TS: m-cresol, purity > 99 % (obtained from Aldrich Chemical<br />

Company)<br />

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