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m-Cresol - ipcs inchem

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OECD SIDS<br />

m- / p-CRESOL MIXTURE<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 15831-10-4<br />

DATE: 24.05.2004<br />

Method : Bench-scale experiments with contaminated soil.<br />

Determination of passive evaporation and biodegradation of<br />

cresols<br />

Result : passive evaporation half-life 4.2 - 4.8 weeks<br />

biodegradation: after 4 days below detection limit<br />

Test condition : Passive evaporation: plastic petri plates (88x18 mm) placed<br />

on canopy-covered table. Temp. 10-17 degrees C, humidity 75%<br />

Shake-flask biodegradation test: 8-25 g soil mixed with 50<br />

ml buffer solution; shaken for 4 days<br />

Reliability : (3) invalid<br />

Methodological deficiencies<br />

11.02.2003 (16)<br />

Type : laboratory<br />

Radiolabel : yes<br />

Concentration :<br />

Soil temperature : °C<br />

Soil humidity :<br />

Soil classification :<br />

Year :<br />

Deg. product :<br />

Method : other: see Method below<br />

Year : 1985<br />

GLP : no<br />

Test substance : other TS: m-cresol<br />

Method : Inocolum: subsurface microbial community of a pristine<br />

aquifer (Lula, Okla.)<br />

Soil: aquifer solid sample, unconsilated sand, from a depth<br />

of 4.5-5.6 m below surface<br />

All substances were radiolabeled.<br />

Incubation period: 8 months<br />

Determination of mineralization via 14CO2 evolution<br />

Remark : The highest percent biodegradation achieved for nearly all<br />

the substances tested was 35% (e.g. anilin, which is the<br />

standard reference substance for all ready tests in OECD 301<br />

achieved after 100 days only 15% biodegradation).<br />

Result : - After 160 days and at a concentration of 39 ng/g m-cresol<br />

in soil, ca.15% mineralization was observed.<br />

- The percent mineralized increased slowly and linearly with<br />

time.<br />

- For the majority of the test compounds no adaptation<br />

period was observed.<br />

Reliability : (3) invalid<br />

No standard test procedure. Test design can only be used to<br />

assess degradation in soil of the pristine aquifer of Lula,<br />

Okla.<br />

11.02.2003 (17)<br />

3.2.1 MONITORING DATA<br />

Type of measurement : other: contamination at a special working place<br />

Media :<br />

Concentration :<br />

Method :<br />

Remark : Combined m-/p-cresol isomers were detected among other<br />

chemicals in the indoor air at a shale oil wastewater<br />

facility at a concentration of 5.1 ppb.<br />

UNEP PUBLICATIONS 311

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