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m-Cresol - ipcs inchem

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OECD SIDS<br />

m-CRESOL<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 108-39-4<br />

DATE: 24.05.2004<br />

Result : - After 160 days and at a concentration of 39 ng/g m-cresol in soil, ca.15%<br />

mineralization was observed.<br />

- The percent mineralized increased slowly and linearly with time.<br />

- For the majority of the test compounds no adaptation period was<br />

observed.<br />

Reliability : (3) invalid<br />

No standard test procedure. Test design can only be used to assess<br />

degradation in soil of the pristine aquifer of Lula, Okla.<br />

15.01.2003 (28)<br />

3.2.1 MONITORING DATA<br />

Type of measurement : other: contamination at a special working place<br />

Media :<br />

Concentration :<br />

Method :<br />

Remark : Combined m-/p-cresol isomers were detected among other chemicals in<br />

the indoor air at a shale oil wastewater facility at a concentration of 5.1 ppb.<br />

Reliability : (2) valid with restrictions<br />

Basic data given<br />

20.01.2003 (29)<br />

3.2.2 FIELD STUDIES<br />

3.3.1 TRANSPORT BETWEEN ENVIRONMENTAL COMPARTMENTS<br />

Type : volatility<br />

Media : water - air<br />

Air : % (Fugacity Model Level I)<br />

Water : % (Fugacity Model Level I)<br />

Soil : % (Fugacity Model Level I)<br />

Biota : % (Fugacity Model Level II/III)<br />

Soil : % (Fugacity Model Level II/III)<br />

Method : other: measured<br />

Year : 1999<br />

Method : Thermodynamic column method of Brunner et al. 1990 applied [Brunner S,<br />

Hornung E, Santl H, Wolff E, Pringer OG, Altschuh J, Brueggemann R<br />

(1990) Henry´s law constants for polychlorinated biphenyls: Experimental<br />

determination and structure-property relationship. Environ Sci Technol 24,<br />

1751 - 1754]:<br />

- Aqueous solution of the TS produced in a generator column<br />

- Solution is passed through gas liquid desorption column where it contacts<br />

a gas stream and the partition equilibrium is reached<br />

- Gas and water are separated: water flows to the receiver dosing funnel,<br />

the gas is conducted into an absorption vessel where the TS is absorbed in<br />

organic solvent<br />

Result : Henry's law constant (25 degrees C):<br />

H = 3.5 E-5 calculated to<br />

H = 8.67 E-2 Pa.m3.mol-1<br />

Test condition : - Temperature 25 °C<br />

- Gas phase: Nitrogen<br />

- Liquid phase: Demineralized, distilled water<br />

- Analysis: GC/ECD<br />

UNEP PUBLICATIONS 77

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