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m-Cresol - ipcs inchem

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OECD SIDS<br />

m-CRESOL<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 108-39-4<br />

DATE: 24.05.2004<br />

3.1.1 PHOTODEGRADATION<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

INDIRECT PHOTOLYSIS<br />

Sensitizer : OH<br />

Conc. of sensitizer : 500000 molecule/cm³<br />

Rate constant : .00000000000873 cm³/(molecule*sec)<br />

Degradation : 50 % after 6 hour(s)<br />

Deg. product :<br />

Method : other (calculated): with SRC-AOPWIN, v1.90<br />

Year : 2003<br />

GLP :<br />

Test substance :<br />

Remark : The calculated half-life is based on a mean OH radical concentration of<br />

0.5E+6 OH radicals/cm3 given during the 24 hours/day as suggested in the<br />

EU-Technical Guidance Document<br />

Reliability : (2) valid with restrictions<br />

Generally accepted calculation method<br />

Flag : Critical study for SIDS endpoint<br />

10.05.2004 (18)<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

Method : other (measured)<br />

Year : 1995<br />

GLP : no data<br />

Test substance : other TS: m-cresol, purity > 99 %<br />

Method : Determination of the temperature-dependency of the<br />

OH-radical reaction under simulated tropospheric conditions<br />

Remark : With a OH radical concentration of 1 000 000 molec cm-3 and<br />

a temperature of 299 K, the half-life is 3.8 h<br />

Result : kOH = 5.17 x 10E-12 exp[(686+-231)/T] cm3 molec.-1 s-1 for a<br />

temperature range of 299-373 K<br />

Test condition : test substance concentration 0.05-5 ppm<br />

reference compound (o-cresol) 0.05-2.3 ppm<br />

radical source methylnitrite 1.5-11 ppm together with NOx<br />

2-70 ppm<br />

Reliability : (1) valid without restriction<br />

Test procedure in accordance with generally accepted<br />

scientific standards; detailed documentation of test<br />

procedure and test conditions<br />

Flag : Critical study for SIDS endpoint<br />

11.05.2004 (19)<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

UNEP PUBLICATIONS 73

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