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m-Cresol - ipcs inchem

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OECD SIDS<br />

p-CRESOL<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 106-44-5<br />

DATE: 24.05.2004<br />

Concentration : 54 mg/l related to Test substance<br />

related to<br />

Deg. product : yes<br />

Method :<br />

Year : 1989<br />

GLP : no<br />

Test substance : other TS: p-cresol, no purity reported<br />

Deg. products : 74-82-8 200-812-7 methane<br />

Method : black anoxic mud collected from a river inoculated in a<br />

mineral medium (10% w/v)<br />

Result : non-acclimated consortia: turnover rate 3.00 µmol/day/g<br />

sediment dw (lag-phase 12 d)<br />

acclimated consortia: turnover rate 6.00 µmol/day/g sediment dw (lagphase<br />

0 d, based on a 24 days incubation period), the CH4 production was<br />

97% of the theoretically possible yield<br />

Test condition : incubation at 28 degrees C in the dark<br />

cultures were refed with 60 mg/l test substance every 2-4 w<br />

for a total of 18 months<br />

Reliability : (2) valid with restrictions<br />

Study in accordance with generally accepted scientific<br />

standards and described in sufficient detail<br />

07.05.2004 (69)<br />

Type : anaerobic<br />

Inoculum : other: unacclimated sediments<br />

Concentration : 1 mmol/l related to Test substance<br />

related to<br />

Contact time :<br />

Degradation : 100 (±) % after 30 day(s)<br />

Result :<br />

Deg. product : yes<br />

Method :<br />

Year : 1990<br />

GLP : no<br />

Test substance : other TS: p-cresol, no purity reported (obtained from Aldrich)<br />

Deg. products : 123-08-0 204-599-1 4-hydroxybenzaldehyde<br />

65-85-0 200-618-2 benzoic acid<br />

74-82-8 200-812-7 methane<br />

99-96-7 202-804-9 4-hydroxybenzoic acid<br />

Method : Sediment samples from a freshwater pond; degradation tested<br />

under three reducing conditions: denitrifying, sulfidogenic, and<br />

methanogenic<br />

Result : TS was completely utilized within 21 to 30 days in unacclimated sediment.<br />

p-<strong>Cresol</strong> degradation proceeded through p-hydroxybenzaldehyde and p-<br />

hydroxybenzoate under methanogenic and denitrifying conditions. Under<br />

methanogenic conditions, also dehydroxylation to benzoic acid took place<br />

Test condition : 30 degrees C in the dark<br />

Reliability : (2) valid with restrictions<br />

No standard test procedure, but in accordance with generally accepted<br />

scientific standards and described in sufficient detail<br />

07.05.2004 (70)<br />

Type : anaerobic<br />

Inoculum : other: acclimated sediments<br />

Concentration : 1 mmol/l related to Test substance<br />

related to<br />

Contact time :<br />

Degradation : 100 (±) % after 10 day(s)<br />

Result :<br />

UNEP PUBLICATIONS 217

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