m-Cresol - ipcs inchem

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OECD SIDS m- / p-CRESOL MIXTURE 3. ENVIRONMENTAL FATE AND PATHWAYS ID: 15831-10-4 DATE: 24.05.2004 3.1.1 PHOTODEGRADATION 308 Type : air Light source : Light spectrum : nm Relative intensity : based on intensity of sunlight Deg. product : Method : other (measured) Year : 1995 GLP : no data Test substance : other TS: m-cresol, purity > 99 % Method : Determination of the temperature-dependency of the OH-radical reaction under simulated tropospheric conditions Remark : With a OH radical concentration of 1 000 000 molec cm-3 and a temperature of 299 K, the half-life is 3.8 h Result : kOH = 5.17 x 10E-12 exp[(686+-231)/T] cm3 molec.-1 s-1 for a temperature range of 299-373 K Test condition : test substance concentration 0.05-5 ppm reference compound (o-cresol) 0.05-2.3 ppm radical source methylnitrite 1.5-11 ppm together with NOx 2-70 ppm Reliability : (1) valid without restriction Test procedure in accordance with generally accepted scientific standards; detailed documentation of test procedure and test conditions Flag : Critical study for SIDS endpoint 12.05.2004 (8) Type : air Light source : Light spectrum : nm Relative intensity : based on intensity of sunlight Deg. product : Method : other (measured): critical review Year : 1994 GLP : no data Test substance : other TS: m-cresol, no purity reported Remark : With a OH radical concentration of 1 000 000 molec/cm3, the half-life is 3.0 h at room temperature Result : K[OH] = 64 [10E-12 cm3 molecule-1 s-1] K[NO3] = 9.74[10E-12 cm3 molecule-1 s-1] K[O3] = 1.9 [10E-19 cm3 molecule-1 s-1] Reliability : (1) valid without restriction Critical review, evaluation of all available experimental data Flag : Critical study for SIDS endpoint 11.05.2004 (9) Type : air Light source : Light spectrum : nm Relative intensity : based on intensity of sunlight Deg. product : Method : other (measured) Year : 1990 GLP : no data Test substance : other TS: m-cresol, purity > 99 % (obtained from Aldrich Chemical Company) UNEP PUBLICATIONS
OECD SIDS m- / p-CRESOL MIXTURE 3. ENVIRONMENTAL FATE AND PATHWAYS ID: 15831-10-4 DATE: 24.05.2004 Method : smog chamber experiment with black light irradiation dry air pressure 735 Torr Temp. 296+-2 K irradiation time 4-20 min reference substance: propene OH radical concentration: (1-3) x 10E7 molecule cm-3 Result : k[OH] = 67.8 [10E-12 cm3 molecule-1 s-1] Reliability : (1) valid without restriction Test procedure in accordance with generally accepted scientific standards; detailed documentation of test procedure and test conditions 11.05.2004 (10) Type : air Light source : Light spectrum : nm Relative intensity : based on intensity of sunlight Deg. product : Method : Year : 1987 GLP : no data Test substance : other TS: m-cresol, no purity reported Method : I. Smog chamber experiment II. Inkrement method Result : m-cresol: I. observed: k[OH] = 57 [10E-12 cm3 molecule-1 s-1] II. calculated: k[OH] = 94 [10E-12 cm3 molecule-1 s-1] Reliability : (1) valid without restriction Test procedure in accordance with generally accepted scientific standards; detailed documentation of test procedure and test conditions 12.05.2004 (11) Type : air Light source : Light spectrum : nm Relative intensity : based on intensity of sunlight Deg. product : Method : other (measured) Year : 1978 GLP : no data Test substance : other TS: m-cresol, no purity reported Method : smog chamber Temp. 300 +-1 K reference substances: n-butane, neopentane initial concentration ca. 0.25 ppm for m-cresol OH radical concentration: (1-4)x10E6 molecule cm-3 Result : k[OH] = 67 [10E-12 cm3 molecule-1 s-1] Reliability : (1) valid without restriction Test procedure in accordance with generally accepted scientific standards; detailed documentation of test procedure and test conditions 12.05.2004 (12) (13) Type : air Light source : Light spectrum : nm Relative intensity : based on intensity of sunlight UNEP PUBLICATIONS 309
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OECD SIDS m- / p-CRESOL FOREOWRD IN
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OECD SIDS m- / p-CRESOL 11. Comment
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OECD SIDS m- / p-CRESOL of mice. In
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OECD SIDS m- / p-CRESOL SIDS Initia
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OECD SIDS m- / p-CRESOL Table 3: Es
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OECD SIDS m- / p-CRESOL m-cresol an
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OECD SIDS m- / p-CRESOL extensive s
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OECD SIDS m- / p-CRESOL et al. 1993
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OECD SIDS m- / p-CRESOL study in wh
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OECD SIDS m- / p-CRESOL Conclusion:
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OECD SIDS m- / p-CRESOL Table 5: m-
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OECD SIDS m- / p-CRESOL ≥300 ppm,
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OECD SIDS m- / p-CRESOL Atrophy and
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OECD SIDS m- / p-CRESOL p-Cresol p-
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OECD SIDS m- / p-CRESOL 3.1.7 Carci
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OECD SIDS m- / p-CRESOL weights wer
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OECD SIDS m- / p-CRESOL drowsiness,
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OECD SIDS m- / p-CRESOL and reduced
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OECD SIDS m- / p-CRESOL The most se
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OECD SIDS m- / p-CRESOL Table 14: T
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OECD SIDS m- / p-CRESOL Table 15: T
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OECD SIDS m- / p-CRESOL 5 RECOMMEND
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OECD SIDS m- / p-CRESOL BRRC (Bushy
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OECD SIDS m- / p-CRESOL Hamster Ova
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OECD SIDS m- / p-CRESOL Nobel W, Ma
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OECD SIDS m- / p-CRESOL Vernot EH,
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OECD SIDS m- / p-CRESOL Available P
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OECD SIDS m- / p-CRESOL √ informa
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OECD SIDS m-CRESOL 1. GENERAL INFOR
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OECD SIDS m-CRESOL 2. PHYSICO-CHEMI
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OECD SIDS m-CRESOL 3. ENVIRONMENTAL
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OECD SIDS m-CRESOL 4. ECOTOXICITY I
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OECD SIDS m-CRESOL 6. REFERENCES ID
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OECD SIDS p-CRESOL 1. GENERAL INFOR
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