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m-Cresol - ipcs inchem

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OECD SIDS<br />

m-CRESOL<br />

3. ENVIRONMENTAL FATE AND PATHWAYS ID: 108-39-4<br />

DATE: 24.05.2004<br />

Method : other (measured): critical review<br />

Year : 1994<br />

GLP : no data<br />

Test substance : other TS: m-cresol, no purity reported<br />

Remark : With a OH radical concentration of 1 000 000 molec/cm3, the<br />

half-life is 3.0 h at room temperature<br />

Result : K[OH] = 64 [10E-12 cm3 molecule-1 s-1]<br />

K[NO3] = 9.74[10E-12 cm3 molecule-1 s-1]<br />

K[O3] = 1.9 [10E-19 cm3 molecule-1 s-1]<br />

Reliability : (1) valid without restriction<br />

Critical review, evaluation of all available experimental<br />

data<br />

Flag : Critical study for SIDS endpoint<br />

11.05.2004 (20)<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

Method : other (measured)<br />

Year : 1990<br />

GLP : no data<br />

Test substance : other TS: m-cresol, purity > 99 % (obtained from Aldrich Chemical<br />

Company)<br />

Method : smog chamber experiment with black light irradiation<br />

dry air pressure 735 Torr<br />

Temp. 296+-2 K<br />

irradiation time 4-20 min<br />

reference substance: propene<br />

OH radical concentration: (1-3) x 10E7 molecule cm-3<br />

Result : k[OH] = 67.8 [10E-12 cm3 molecule-1 s-1]<br />

Reliability : (1) valid without restriction<br />

Test procedure in accordance with generally accepted<br />

scientific standards; detailed documentation of test<br />

procedure and test conditions<br />

11.05.2004 (21)<br />

Type : air<br />

Light source :<br />

Light spectrum : nm<br />

Relative intensity : based on intensity of sunlight<br />

Deg. product :<br />

Method : other (measured)<br />

Year : 1987<br />

GLP : no data<br />

Test substance : other TS: m-cresol, no purity reported<br />

Method : I. Smog chamber experiment<br />

II. Inkrement method<br />

Result : I. observed: k[OH] = 57 [10E-12 cm3 molecule-1 s-1]<br />

II. calculated: k[OH] = 94 [10E-12 cm3 molecule-1 s-1]<br />

Reliability : (1) valid without restriction<br />

Test procedure in accordance with generally accepted<br />

scientific standards; detailed documentation of test<br />

procedure and test conditions<br />

11.05.2004 (22)<br />

74<br />

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