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Benders'dictionary of nutrition and food technology

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184bonds (e.g. C18:2), followed by the position <strong>of</strong> the first doublebond from the methyl end <strong>of</strong> the molecule as n- or ω (e.g. C18:2n-6, or C18:2 ω6). See Table 8 <strong>of</strong> the Appendix.fatty acids, essential (EFA) fatty acids that cannot be made inthe body <strong>and</strong> are therefore dietary essentials – two polyunsaturatedfatty acids: linoleic (C18:2 ω6) <strong>and</strong> α-linolenic (C18:3 ω3).Several other fatty acids have some EFA activity in that theycure some, but not all, <strong>of</strong> the signs <strong>of</strong> (experimental) EFA deficiency.Arachidonic (C20:4 ω6), eicosapentaenoic (EPA C20:5ω3) <strong>and</strong> docosahexaenoic (DHA C22:6 ω3) acids are physiologicallyimportant, although they are not dietary essentials sincethey can be formed from linoleic <strong>and</strong> α-linolenic acids.Estimated average requirement for ω6 PUFA is 1% <strong>of</strong> totalenergy intake (260 mg/MJ) <strong>and</strong> for ω3 PUFA is 0.2% (50 mg/MJ),with a recommendation that total PUFA intakes should notbe more than 10–15% <strong>of</strong> total energy; a desirable intake, <strong>and</strong> thebasis <strong>of</strong> reference intakes, is 8–10% <strong>of</strong> energy intake, about2–2.6 g/MJ.fatty acids, free (FFA) or non-esterified (NEFA) Fatty acids maybe liberated from triacylglycerols (triglycerides) either byenzymic hydrolysis (when they are generally known as nonesterifiedfatty acids, NEFA, or unesterified fatty acids, UFA) oras a result <strong>of</strong> hydrolytic rancidity <strong>of</strong> the fat. Determination <strong>of</strong>NEFA is therefore an index <strong>of</strong> the quality <strong>of</strong> fats.Free fatty acids circulate in the bloodstream, bound toalbumin. They are released from adipose tissue in the fastingstate, as a fuel for muscle <strong>and</strong> other tissues. The normal concentrationin plasma is between 0.5 <strong>and</strong> 2 µmol/L, increasing withfasting <strong>and</strong> exercise.fatty acids, polyunsaturated Long-chain fatty acids containingtwo or more double bonds, separated by methylene bridges:—CH 2 —CH=CH — CH 2 —CH=CH — CH 2 —.fatty acids, unesterified, non-esterified (NEFA) See fatty acids,free.fatty acids, volatile Short-chain fatty acids, acetic, propionic <strong>and</strong>butyric, which, apart from their presence in some <strong>food</strong>s, areproduced by bacteria in the human intestine <strong>and</strong> rumen <strong>of</strong>cattle from undigested starch <strong>and</strong> dietary fibre. To someextent they can be absorbed <strong>and</strong> used as a source <strong>of</strong> energy.Butyric acid formed in the colon may have some anticarcinogenicaction, <strong>and</strong> is a significant metabolic fuel for colonicenterocytes.fat, unsaturated fats containing a high proportion <strong>of</strong> unsaturatedfatty acids.fat, yellow See spread, fat.

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