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A Guide to the Russian Academy of Sciences - University of Texas ...

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1960s plasma chemistry--a new field <strong>of</strong> chemical science--originated in <strong>the</strong> institute.<br />

New ideas <strong>of</strong> non equilibrium chemical kinetics were developed, new approaches,<br />

experimental l, and <strong>the</strong>oretical methods were introduced and <strong>the</strong> mechanisms <strong>of</strong> <strong>the</strong><br />

physical and chemical processes in non equilibrium and quasi-equilibrium plasmas<br />

were systematically studied. Under <strong>the</strong> action <strong>of</strong> low-temperature plasma on <strong>the</strong><br />

surface <strong>of</strong> various polymers, protective, optical and hydrophilic coatings for<br />

materials <strong>of</strong> medical, biomedical, and membrane technology applications are created<br />

and valuable materials for microelectronics and micro-engineering industries have<br />

been developed. Pr<strong>of</strong>essors L. S. Polak and D. I. Slovetskii have provided <strong>the</strong><br />

leadership in this new field <strong>of</strong> study and research. Academician Pr<strong>of</strong>essor<br />

(academician <strong>of</strong> <strong>the</strong> General and Technical Chemistry Department <strong>of</strong> <strong>the</strong> <strong>Russian</strong><br />

<strong>Academy</strong> <strong>of</strong> <strong>Sciences</strong>) B. A. Dolgoplosk, V. A. Iakovlev, D. Chem. S., Pr<strong>of</strong>essor<br />

V. M. Frolov, and Pr<strong>of</strong>essor K. K. Makovetskii have headed <strong>the</strong> widely known<br />

work in <strong>the</strong> institute in <strong>the</strong> fields <strong>of</strong> organo-metallic catalysis, stereo specific<br />

polymerization <strong>of</strong> dienes and cyclo-olefins, and <strong>the</strong> chemistry <strong>of</strong> polyolefins--all<br />

used in application in industrial syn<strong>the</strong>sis <strong>of</strong> a number <strong>of</strong> rubbers and polyolefins.<br />

New <strong>the</strong>rmoresistant polyolefins are being syn<strong>the</strong>sized and investigated.<br />

Academician Pr<strong>of</strong>essor N. A. Plate (academician <strong>of</strong> <strong>the</strong> General and Technical<br />

Chemistry Department <strong>of</strong> <strong>the</strong> <strong>Russian</strong> <strong>Academy</strong> <strong>of</strong> <strong>Sciences</strong>) and L. I. Valuev, D.<br />

Chem. S., Head up <strong>the</strong> search for scientific approaches for producing polymeric<br />

materials for medicine and, in particular, materials for artificial limbs--polymers<br />

with oriented physiological activity are being investigated. In oxygeno<strong>the</strong>rapy,<br />

original membranes and corresponding installations for air enrichment with oxygen<br />

are developed and successfully used. On <strong>the</strong> basis <strong>of</strong> chemistry <strong>of</strong> macromonomers<br />

<strong>of</strong> physiologically active compounds, <strong>the</strong> principles for <strong>the</strong> creation <strong>of</strong> hydrogel<br />

polymeric sorbents for organism de<strong>to</strong>xification, for manufacturing hemocompatible<br />

coatings for implantation are being developed. An original "Ovosorb" sorbent for<br />

curing pancreatitis, asthma, sepsis, and o<strong>the</strong>r diseases has been developed.<br />

Hydrogeanti-glaucoma drains have been developed and are produced in <strong>the</strong> Institute<br />

for surgery. Modified copolymers <strong>of</strong> maleic anhydride with antiviral, immunostimulating,<br />

and anti-tumoral activity are syn<strong>the</strong>sized and are successfully tested.<br />

Pr<strong>of</strong>essor D. A. Topchiev and F. A. Gembitskii, D. Chem. S. have lead <strong>the</strong><br />

fundamental research in <strong>the</strong> syn<strong>the</strong>sis <strong>of</strong> water-soluble polymers and have<br />

developed a number <strong>of</strong> original cationic polyelectrolytes whose production has been<br />

commercialized in industry. These polyelectrolytes are used for flocculation <strong>of</strong><br />

industrial drain waters, in <strong>the</strong> production <strong>of</strong> effective detergents, for structuring<br />

soils, and for antiseptation <strong>of</strong> animals, meals, hospital environments, etc. Pr<strong>of</strong>essor<br />

A. D. Litmanovich and Academician Plate Head up <strong>the</strong> institute's work in <strong>the</strong> field<br />

<strong>of</strong> macromolecular reactions <strong>the</strong>ory: intra-and intermolecular reactions in polymer<br />

melts, glasses, and polymer mixtures. Work is underway in <strong>the</strong> creation <strong>of</strong><br />

macromolecular catalysts and reagents for organic syn<strong>the</strong>sis. The polymerization<br />

processes <strong>of</strong> various unsaturated organo-element monomers has been intensively<br />

pursued in <strong>the</strong> institute for <strong>the</strong> last 30 years under <strong>the</strong> direction <strong>of</strong> Dr. V. S.<br />

Khotimskii, Dr. V. V. Volkov, Dr. V. V. Tepliakov, and Academician Plate. At <strong>the</strong><br />

end <strong>of</strong> <strong>the</strong> 1960s, a process for <strong>the</strong> production <strong>of</strong> a poly (vinyltrimethylsilane)<br />

membrane with high gas permeability and selectivity parameters was developed.<br />

Research and development projects are completed developing membranes from poly<br />

(trimethylsilylpropyne) that have proved <strong>to</strong> be not only superior for gas separation,<br />

but can be used for pervaporation. Institute labora<strong>to</strong>ries are equipped with<br />

au<strong>to</strong>mated plants for membrane manufacture, plasma chemical modification and<br />

measurement <strong>of</strong> permeability parameters. Investigations in <strong>the</strong> institute in <strong>the</strong> field<br />

<strong>of</strong> liquid crystal (LC) polymers are aimed at <strong>the</strong> development <strong>of</strong> unique rigid<br />

chemical structures. Reinforced blends <strong>of</strong> <strong>the</strong>rmoplastics with LD-polymers<br />

increases <strong>the</strong> strength <strong>of</strong> polymeric materials by two or three times producing a new<br />

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