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A Guide to the Russian Academy of Sciences - University of Texas ...

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Secretary <strong>of</strong> Foreign Scientific Relations<br />

Dr. Inna K. Kuznetsova<br />

135-9278<br />

Direc<strong>to</strong>r Assistant <strong>of</strong> Foreign Economic Relations<br />

Dr. Nina M. Chis<strong>to</strong>valova 135-<br />

6550<br />

Direc<strong>to</strong>r Assistant <strong>of</strong> Patent Laws<br />

Dr. Alla N. Chumaevskaya<br />

Organoelement Division<br />

Labora<strong>to</strong>ry for Organometallic Compounds<br />

Head <strong>of</strong> labora<strong>to</strong>ry-- Pr<strong>of</strong>essor Dmitrii N. Kravtsov<br />

135-9202<br />

The labora<strong>to</strong>ry was set up in 1935 at <strong>the</strong> Institute <strong>of</strong> Organic Chemistry <strong>of</strong> <strong>the</strong> USSR<br />

<strong>Academy</strong> <strong>of</strong> <strong>Sciences</strong>. In 1954 it became a division <strong>of</strong> INEOS. Pr<strong>of</strong>essor A. N.<br />

Nesmeyanov (Nesmeianov) headed <strong>the</strong> labora<strong>to</strong>ry from its organization until his<br />

death in 1980.<br />

Investigations in <strong>the</strong> field <strong>of</strong> physical organometallic chemistry. Studies on <strong>the</strong> properties <strong>of</strong><br />

univalent organometallic groups containing central a<strong>to</strong>ms <strong>of</strong> transition or heavy<br />

main group metals involving ?-bond polarity, comparative electronegativity and<br />

chemical hardness as well as structure <strong>of</strong> potentially metallotropic systems. Spectral<br />

investigations <strong>of</strong> novel types <strong>of</strong> hydrogen bonding and <strong>the</strong>ir role in pro<strong>to</strong>nation <strong>of</strong><br />

transition metal ?-complexes and hydrides.<br />

Labora<strong>to</strong>ry for Transition Metal p-Complexes<br />

Head <strong>of</strong> labora<strong>to</strong>ry-- Pr<strong>of</strong>essor Margarita I. Rybinskaia (aya)<br />

The labora<strong>to</strong>ry was founded in 1978. Syn<strong>the</strong>sis <strong>of</strong> neutral and cationic mono- and<br />

polynuclear complexes including clusters with organic p-ligands. Investigation <strong>of</strong><br />

<strong>the</strong>ir structure and reactivity with <strong>the</strong> aim <strong>of</strong> obtaining polydecker and sandwich<br />

cluster compounds. Elucidation <strong>of</strong> <strong>the</strong> mechanism responsible for stabilization <strong>of</strong> pcarbocationic<br />

center by metallocomplex fragment and syn<strong>the</strong>sis <strong>of</strong> <strong>the</strong> first stable<br />

metallonium mono- and di-cations on <strong>the</strong> base <strong>of</strong> permethylated metallocenes.<br />

Labora<strong>to</strong>ry for Stereochemistry <strong>of</strong> Organometallic Compounds<br />

Head <strong>of</strong> labora<strong>to</strong>ry-- Pr<strong>of</strong>essor Viacheslav I. Sokolov<br />

The labora<strong>to</strong>ry was set up in 1989. Development <strong>of</strong> new methods for preparing optically<br />

active organometallic compounds, investigation <strong>of</strong> <strong>the</strong>ir chiroptical properties.<br />

Application <strong>of</strong> enantiomeric organometallic derivatives <strong>of</strong> transition metals for<br />

asymmetric syn<strong>the</strong>sis <strong>of</strong> organic compounds. Syn<strong>the</strong>sis <strong>of</strong> organometallic<br />

derivatives <strong>of</strong> fullerenes, including optically active ones. Syn<strong>the</strong>sis <strong>of</strong> optically<br />

active porphyrins with pendant chiral organometallic substituents.<br />

Labora<strong>to</strong>ry for Organoaluminium and Organoboron Compounds<br />

Head <strong>of</strong> labora<strong>to</strong>ry-- Pr<strong>of</strong>essor Vladimir I. Bregadze<br />

414

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