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Fac-simile Scheda Linee di Ricerca - Federalimentare

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Dati pubblicati inerenti il tema <strong>di</strong> ricerca:1. Valentini N., Rolle L., Stévigny C., Zeppa G. (2006) Mechanical behaviour of hazelnuts usedfor table consumption under compression loa<strong>di</strong>ng. J. Sci. Food Agric 2006, 86 (8), 1257-1262.Nuts of four hazelnut varieties and five new selections used for table consumption were compressed at the moisturecontent of 6% wet basis to measure shell resistance to breakage. Rupture force, rupture energy and nut specificdeformation were measured under three compression loa<strong>di</strong>ng positions. Physical parameters of nuts werealso evaluated to relate them to the data obtained by compression test measurements. Rupture force and nut specificdeformation are the most <strong>di</strong>scriminant parameters that can be used to describe the behaviour under compression,while rupture energy values show fewer <strong>di</strong>fferences among the considered varieties. The values of force requiredto break nut shell ranged from 322.2 to 769.3 N. The lowest values of force were generally obtained alongthe y-axis, the transverse axis containing the major <strong>di</strong>mension at right angles to the longitu<strong>di</strong>nal axis. Nut specificdeformation ranged from 3.35 to 11.76%. Correlations between physical and texture parameters showed that valuesof force, energy and deformation were dependent on <strong>di</strong>fferent parameters that varied in the three consideredaxis. The most used varieties, Ennis and Barcelona, showed high mean values of force rupture to break shell andlow deformability, while Tonda Giffoni and Tonda Bianca were easy to break. Among the new selections, L35and B6, with mean values of force rupture less than 428 N and values of nut specific deformation higher than8%, were suitable for table consumption.2. Stevigny C., Rolle L., Valentini N., Zeppa G. (2007) Optimization of extraction of phenoliccontent from hazelnut shell using response surface methodology. J Sci Food Agric, 87, 2817-2822Response surface methodology was applied to pre<strong>di</strong>ct the optimum con<strong>di</strong>tions for extraction of phenolic compoundsin hazelnut shell. The phenolic content in the shell extract was determined spectrophotometrically accor<strong>di</strong>ngto the Folin-Ciocalteu method and expressed as gallic acid equivalent (mg GAE g−1). Two central compositedesigns were used to investigate the effects of two independent variables, namely solvent composition (%)and extraction time (min), on phenolic extraction. In a first series of repeated batch extractions, the solvent consistedof <strong>di</strong>fferent methanol percentages in <strong>di</strong>stilled water at pH 4, while in a second series methanol was substitutedby ethanol. The highest phenolic content (6.67mg GAE g−1 of shell) was pre<strong>di</strong>cted at the extraction con<strong>di</strong>tionsof 55.7% ethanol and 108.7min. These best con<strong>di</strong>tions, obtained and applied to 13 <strong>di</strong>fferent cultivars,showed values varying from 9.18mg GAE g −1 of shell for Barcelona to 3.00mg GAE g −1 of shell for Tonda <strong>di</strong>Giffoni.3. Prosperini S., Ghirardello D., Scursatone B., Gerbi V., Zeppa G. (2008) Identification of solublephenolic acids in hazelnut (Corylus avellana L.) kernel. 7° International Congress on hazelnut,Viterbo (I), 23-27 June, P5-12-63A, 170.Phenolic acids are a subclass of a larger category of compounds commonly referred to as “phenolics”. They are avery important group of secondary plant metabolites whose roles are still unknown. Due to their antioxidant behaviourand the potential health benefits associated with these simple phenolic compounds, many authors haveproposed <strong>di</strong>fferent techniques to extract these compounds from vegetable foods. Therefore, the aim of this workis to compare the experimental con<strong>di</strong>tions commonly used to detect soluble phenolic acids (both free and esterified)in order to investigate the phenolic constituents in hazelnut kernel extracts. Phenolic compounds present indefatted samples were extracted using <strong>di</strong>fferent solvent mixtures under reflux con<strong>di</strong>tions at <strong>di</strong>fferent temperatures;afterwards, the extraction and hydrolysis of phenolic acids was performed. HPLC analysis of the extractsobtained highlighted the presence of twelve phenolic acids. The main compounds identified were gallic acid, caffeicacid, p-cumaric acid, ferulic acid and sinapic acid. In all extracts, gallic acid was the most abundant, in boththe free and esterified form. Ethanol solution (80% v/v) at 80 °C was the most effective solvent for the quantitativeextraction of benzoic acid derivatives, but extract obtained with acetone solution (80% v/v) at 50 °C showedthe highest number of identified phenolic acids. All the other suggested methods showed low extraction capacityfor these compounds. Using these optimized methods, new researches are in progress to define the effect of storageand roasting on these compounds.SISTAL - SOCIETA’ ITALIANA DI SCIENZE E TECNOLOGIE ALIMENTARIDipartimento <strong>di</strong> Scienze e Tecnologie Agroalimentari, Università degli Stu<strong>di</strong> della TusciaVia San Camillo de Lellis, 01100 ViterboTel.: 0761- 35 74 94/7 , Fax: 0761- 35 74 98, e-mail: mmoresi@unitus.it449

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