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Abstracts Book - IMRC 2018

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• SC4-O019<br />

PHOTOVOLTAIC STRUCTURES USING CuxSnySz AS AN ABSORBER<br />

MATERIAL.<br />

David Avellaneda 1 , Sadasivan Shaji 2 , Bindu Krishnan 2 , Laura Patricia Rivera Rosas 2<br />

1 Universidad Autónoma de Nuevo León, FIME-CIDET, Mexico. 2 Universidad Autónoma de<br />

Nuevo León, FIME, Mexico.<br />

In recent years, the advances in solar energy and particularly in the materials<br />

used for the absorption of solar radiation have had a very remarkable<br />

development. However, we know that no technology or individual material can<br />

solve the problem; for this reason, efforts in research of new materials as well<br />

as processes to improve existing ones, continue to be carried out by various<br />

research groups. Thin films of the system Cu-Sn-S are promising materials in the<br />

field of photovoltaic. In previous work, we obtained thin films of different phases<br />

of such system: Cu2SnS3, Cu3SnS4 and Cu4SnS4 by thermal evaporation of Cu<br />

layer on SnS thin films and thermal treatments in sulfur atmosphere<br />

(sulfurization process) at temperatures of 400-500 °C. In this work, we report the<br />

rapid thermal annealing of those films, their characterization to determine<br />

changes in structural (Raman/XRD), morphological (AFM/SEM), chemical (XPS),<br />

optical (UV-Vis-NIR) and electrical (IV) properties. The thin films with the best<br />

properties are included in a photovoltaic structure, and the principal properties<br />

will be presented.<br />

Acknowledgment:<br />

The authors are thankful to SEP-CONACYT (Project No. 241022) and CEMIE-Sol<br />

Project 35 (CONACYT-SENER), for financial assistance.<br />

Keywords: Cu2SnS3, Cu3SnS4 and Cu4SnS4, Photovoltaic structures, thin films<br />

Presenting authors email: david.avellanedavl@uanl.edu.mx

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