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Abstracts Book - IMRC 2018

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• SC4-P086<br />

CHEMICAL DEPOSITION OF Co +2 DOPED FeS2 THIN FILMS WITH<br />

FERROMAGNETIC PROPERTIES FOR PHOTOVOLTAIC SYSTEMS.<br />

Eder Cedeño 1 , Yolanda Peña 1 , Idalia Gómez 1<br />

1 Universidad Autónoma de Nuevo León, Facultad de Ciencias Químicas, Mexico.<br />

Harnessing the sun’s energy to produce electricity has proven to be one of the<br />

most promising solutions to the world’s energy crisis. However, the device to<br />

convert sunlight to electricity, a solar cell, must be reliable and cost effective in<br />

order to compete with conventional sources.<br />

On the basis of material extraction costs leading to significantly lower cost per<br />

kilowatt-hour, FeS2 is one of the most promising material for photovoltaic<br />

applications. In addition, Iron pyrite (Cubic FeS2) has suitable properties as an<br />

appropriate band gap (Eg≈ 0.95 eV) and very strong light absorption ( a > 10 5 cm -<br />

1<br />

for hn > 1.3 eV) for scalable thin films solar cells.<br />

In the present work, Co +2 doped Iron pyrite thin films were deposited on glass<br />

substrates through chemical bath deposition technique (CBD). Co compositions<br />

were 1 to 5 mole %. These thin films were thermal treated at 250 °C in a high<br />

vacuum oven (6 x10 -3 Torr). The characterization of heat-treated thin films by X-<br />

ray diffraction (XRD) showed the presence of the cubic phase of FeS2. Surface<br />

profilometry characterization displayed a thickness value between 200-450 nm.<br />

The band gap energy Eg was also calculated as 1-1.3 eV. Finally, conductivity was<br />

obtained in the interval of 10 -3 - 0.5 W -1 cm -1 .<br />

Keywords: photovoltaic systems, iron pyrite, chemical bath deposition<br />

Presenting authors email: emcm729@gmail.com

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