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Abstracts Book - IMRC 2018

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• SC4-O022<br />

PROCESSING AND CHARACTERIZATION OF SB2TE3 BY DC-<br />

SPUTTERING DEPOSITION FOR SOLAR CELLS APLICATION<br />

Rogelio Mendoza Pérez 1 , Jose Alfredo del Oso Acevedo 1 , Jorge Sastré Hernández 2 , José Joaquín<br />

Lizardi del Ángel 1 , Guillermo Santana 3 , Gerardo Contreras Puente 2<br />

1<br />

Universidad Autónoma de la Ciudad de México, Colegio de Ciencia y Tecnología, Mexico.<br />

2 Escuela Superior de Física y Matemáticas IPN, Física, Mexico. 3 Instituto de Investigaciones en<br />

Materiales, Instituto de Investigaciones en Materiales,, Mexico.<br />

This work presents results about the deposition and characterization of<br />

antimony telluride (Sb2Te3) thin film grown by DC- sputtering. Sb2Te3 was<br />

deposited varying magnetron power from 10 W to 60 W, the substrate<br />

temperature from room temperature to 300 °C, and the deposition pressure<br />

from 5 to 20 mTorr. Sb2Te3 is used as p+ material on CdTe solar cells because it<br />

improves their efficiency and stability by obtaining a Te-rich region. Energy<br />

dispersive spectrometry (EDS), morphology, resistivity, and profile<br />

measurements were carried out on Sb2Te3 samples. The EDS analyses revealed<br />

that if the pressure decreases to 5 mTorr, the mass quantity and atomic<br />

composition of Te obtained in the thin film composition increases. On the other<br />

hand, when temperature is increased to 300 °C the quantity of Te increases near<br />

3.77 keV and a "sheath"-type structure appeared, with elongated grains of<br />

Sb2Te3. Finally, we found that when the substrate temperature increased the<br />

resistivity decreased slightly to 4.8 × 10 -3 ohm-cm. So for CdTe solar cells<br />

application it is necessary to obtain a Te content in the range 60-70% (atomic);<br />

for this, it is convenient to grow Sb2Te3 by DC-sputtering at low pressure and<br />

relative high temperature, near 300 °C.<br />

Acknowledgment:<br />

The authors wish to express acknowledgment of financial support by CONACyT<br />

under project FOMIX 189282<br />

Keywords: p+ material, back contact, antimony telluride<br />

Presenting authors email: rogeliomp02@gmail.com

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