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Abstracts Book - IMRC 2018

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AFM imaging of the plasma-treated UNCD films revealed no significant change<br />

in the surface roughness after either O2 or CF4 treatments when they were<br />

compared with the surface of the as-grown UNCD films. Nevertheless, a surfacechemistry<br />

alteration was confirmed by XPS, which is directly responsible for the<br />

change in the wettability behavior. On the other hand, a small increase of the<br />

WCA was observed as function of grain size UNCD to MCD films. This effect<br />

provided the bases for exploring an additional process to increase even further<br />

the hydrophobicity of polycrystalline diamond film surfaces. Thus, subsequent<br />

research discussed in this abstract, revealed that the synergistic complementary<br />

effect of 3-D structured + plasma-induced fluorinated surface termination of<br />

UNCD, NCD and MCD films resulted in super-hydrophobic surfaces that<br />

revealed WCA up to 172Ëš, thus producing the highest super-hydrophobic<br />

surface of diamond material demonstrated today.<br />

Acknowledgment:<br />

O. Auciello acknowledges funding his Distinguished Endowed Chair of<br />

University of Texas Dallas<br />

E. de Obaldia acknowledges suport Universidad Tecnológica de Panamá,<br />

Panamá, República de Panamá.<br />

G. Montaño and P. Tirado acknowledge schoarlship support CONACYT-México<br />

Keywords: hydrophilic, hydrophobic, polycrystalline diamond surfaces<br />

Presenting authors email: gabrielamf@gmail.com

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