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Abstracts Book - IMRC 2018

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• SB4-O015 Invited Talk<br />

DEVELOPMENT OF SOLUTION-PROCESSED, LOW-TEMPERATURE<br />

HYBRID FILMS FOR DIELECTRIC GATE APPLICATIONS<br />

Rafael Ramirez Bon 1<br />

1 Centro de Investigación y de Estudios Avanzados del IPN - CINVESTAV, Unidad Querétaro,<br />

Mexico.<br />

Nowadays the increasing interest on organic and flexible electronics has<br />

promoted the research on new semiconductors and dielectric materials,<br />

including hybrid organic-inorganic, for their application in electronic devices.<br />

The main constrain imposed by flexible electronics is the low temperature<br />

processing of the materials, which must be compatible with the low temperature<br />

resistance of the plastic substrates. Therefore, although inorganic materials<br />

perform much better in electronic devices, they are discarded for flexible<br />

electronics because of this constrain. On the other hand, organic materials are<br />

inestable, have disordered structure with low mobility and low dielectric<br />

constant in the case of dielectrics, limiting the performance of the devices.<br />

Regarding dielectric applications, organic-inorganic hybrid materials are a new<br />

approach for the development of dielectric materials, which fulfill the demands<br />

of flexible electronics. Hybrid materials consists in the appropriate combination<br />

of organic and inorganic phases in a new class of materials, which take<br />

advantage on the complementary properties of both constituents, allowing for<br />

the design of materials with specific properties. In this work we present a brief<br />

review of the aplications of hybrid dielectric layers as dielectric gate in thin film<br />

transistor. Then, we describe our research on the development of hybrid<br />

dielectric films for gate layer applications in thin film transistors. The low<br />

temperature sol-gel process consist in the simultaneous polimerization of the<br />

organic component and the hydrolysis and condensation of the inorganic one,<br />

which result in the formation of a cross-linked organic-inorganic hybrid network.<br />

By combining different polymers with high k inorganic dielectrics we obtained<br />

different hybrid dielectric systems with properties depending on the organic to<br />

inorganic content ratio. Finally, we describe the most significant results about<br />

the electrical performance of some hybrid dielectric gate layers in thin film<br />

transistors with different semiconductor material as the active layers.<br />

Keywords: DIELECTRICS, HYBRID MATERIALS, TRANSISTORS<br />

Presenting authors email: rrbon@qro.cinvestav.mx

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