Abstracts Book - IMRC 2018

• SC7-O004 Invited Talk
METAL ORGANIC FRAMEWORKS AS PRECURSORS FOR THE
MANUFACTURE OF ADVANCED CATALYTIC MATERIALS
Jorge Gascon 1
1 King Abdullah University of Science and Technology, PSE, Saudi Arabia.
The development of synthetic protocols for the preparation of highly loaded
metal nanoparticle supported catalysts has received a great deal of attention
over the last few decades. Independently controlling metal loading, nanoparticle
size, distribution and accessibility has proven challenging because of the clear
interdependence between these crucial performance parameters. Among the
different strategies suggested in literature, the use of metal-organic-frameworks
(MOFs) as precursors for the synthesis of catalytic nanomaterials offers
unrivalled design possibilities, 1 as we will demonstrate in this presentation.
Herein we will discuss the application of MOFs as catalyst precursors for the
synthesis of highly loaded metal nanoparticle supported solids for applications
in syngas and CO 2 related chemistries. 2-6 In the last part, we will introduce the
use of MOFs as templates for the synthesis of single site based catalysts with
application in hydrogenation reactions. 7
References:
(1) Oar-Arteta, L.; Wezendonk, T.; Sun, X.; Kapteijn, F.; Gascon, J. Materials
Chemistry Frontiers 2017, 1, 1709.
(2) Santos, V. P.; Wezendonk, T. A.; Jaén, J. J. D.; Dugulan, A. I.; Nasalevich, M. A.;
Islam, H.-U.; Chojecki, A.; Sartipi, S.; Sun, X.; Hakeem, A. A.; Koeken, A. C. J.;
Ruitenbeek, M.; Davidian, T.; Meima, G. R.; Sankar, G.; Kapteijn, F.; Makkee, M.;
Gascon, J. Nature Communications 2015, 6, 6451.
(3) Wezendonk, T. A.; Santos, V. P.; Nasalevich, M. A.; Warringa, Q. S. E.;
Dugulan, A. I.; Chojecki, A.; Koeken, A. C. J.; Ruitenbeek, M.; Meima, G.; Islam,
H.-U.; Sankar, G.; Makkee, M.; Kapteijn, F.; Gascon, J. ACS Catalysis 2016, 3236.
(4) Wezendonk, T. A.; Warringa, Q. S. E.; Santos, V. P.; Chojecki, A.; Ruitenbeek,
M.; Meima, G.; Makkee, M.; Kapteijn, F.; Gascon, J. Faraday Discussions 2017,
197 (1–2), 225.
(5) Sun, X.; Suarez, A. I. O.; Meijerink, M.; Deelen, T.; Ould-Chikh, S.;
Zeĕević, J.; Jong, K. P.; Kapteijn, F.; Gascon, J. Nature Communications
2017, 1.
(6) Sun, X.; Olivos Suarez, A. I.; Oar-Arteta, L.; Rozhko, E.; Osadchii, D.; Bavykina,