Abstracts Book - IMRC 2018

• SF4-O006 Invited Talk
A JOURNEY TO THE SYNTHESIS OF FRUSTRATED LEWIS PAIRS
WITH GROUP 13 COMPOUNDS
Oracio Serrano 1
1 Universidad de Guanajuato, Química, Mexico.
A decade ago, Stephan reported an elegant and unprecent work on olefin
activation through sterically frustrated Lewis pairs (FLP) of phosphines and the
borane [B(C 6 F 5 ) 3 ], with a concomitant renascent of p-bloxk chemistry related to
the transition metal free catalysis. Therefore, Al, Ga, and In congeners, in high
oxidation state, has been olaso considered with promising and fashionable
results. So, most of FLP involves counterparts group 13 and 15, respectively.
However, the synthesis and reactivity of LFP having exclusively group 13
elements are scarce. In this context, we will discuses our results on the synthesis
of FLP containing Al(III) species [Al(Ar F ) 3 ] with Ga(I) or In(I) compounds supported
by m-terphenyl ligands.
Acknowledgment:
Tha authors thank the support provide by Universidad de Guanajuato
Keywords: FLP, Gallium, m-terphenyl
Presenting authors email: oraciosinh@ugto.mx